Non-aqueous electrolyte additive for improving safety and...

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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C429S324000, C429S326000

Reexamination Certificate

active

10312674

ABSTRACT:
The present invention relates to a non-aqueous electrolyte additive for improving safety and a lithium secondary battery comprising the same, and more particularly to a non-aqueous electrolyte additive that can improve cycle life and safety properties of a lithium ion secondary battery.According to the present invention, an organometallic compound represented by the Chemical Formula 1 is added to a non-aqueous electrolyte of a battery as an additive, and thus if a battery voltage is out of normal operation voltage range due to a short circuit and overcharge of a battery, etc., the non-aqueous electrolyte additive decomposes and a part of the decomposed additive polymerizes to form an insulating film on a cathode surface, and a part of the metal reacts with an insulating film formed on a cathode surface to improve thermal stability of the battery, thereby improving safety of the battery. Furthermore, in case of a short circuit a part of the metal oxide of the additive is removed an activity of lithium or is reduced movement speed of lithium by reacting with lithium rushed from an anode to a cathode, and thus safety of the battery can be obtained on a short circuit by delaying a flow of current.

REFERENCES:
patent: 5633098 (1997-05-01), Narang et al.
patent: 6159635 (2000-12-01), Dasgupta et al.
patent: 10-064591 (1998-03-01), None
patent: 11-126632 (1999-05-01), None
patent: 12-058112 (2000-02-01), None
patent: 12-058113 (2000-02-01), None
patent: 12-058115 (2000-02-01), None
Johnstone et al. “Polymer Electrolyte Based on a Dimethylsiloxane-Polyethylene Oxide,” European Polymer Journal, 26(9), 987-90 (1990).

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