Non-aqueous electrolyte additive for improving safety and...

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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C429S306000, C429S324000, C429S336000

Reexamination Certificate

active

10312672

ABSTRACT:
The present invention relates to a non-aqueous electrolyte additive for improving safety and a lithium secondary battery comprising the same, and more particularly to a non-aqueous electrolyte additive that can improve cycle life and safety properties of a lithium ion secondary battery.According to the present invention, an organometallic compound represented by the Chemical Formula 1 is added to a non-aqueous electrolyte of a battery as an additive, and thus if a battery voltage is out of normal operation voltage range due to a short circuit and overcharge of a battery, etc., the non-aqueous electrolyte additive decomposes and a part of the decomposed additive polymerizes to form an insulating film on a cathode surface, and a part of the metal reacts with an insulating film formed on a cathode surface to improve thermal stability of the battery, thereby improving safety of the battery.

REFERENCES:
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Becker et al., Electrochemical Oxidation of deca-n-propylcyclopentasilane [(n-Pr)2Si]5, dodecamethylcyclohexasilane (Me2Si)6 and tetradecaethylcycloheptasilen (Et2Si)7, J. Electroanalytical. Chem., 417 (1996) 77-82.

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