Drug – bio-affecting and body treating compositions – Live hair or scalp treating compositions – Shaving preparation
Reexamination Certificate
2001-07-26
2003-09-30
Venkat, Jyothsna (Department: 1615)
Drug, bio-affecting and body treating compositions
Live hair or scalp treating compositions
Shaving preparation
C514S944000
Reexamination Certificate
active
06627185
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to non-aerosol shaving gel compositions.
An extensive discussion regarding the formulation of various shaving preparations may be found in
Harry's Cosmeticology
, Seventh Edition, J. B. Wilkinson and R. J. Moore (editors), Chemical Publishing, New York, 1982, pp. 156-189. Currently, the most widely used forms of shaving preparation are the types referred to as instant foams and self-foaming gels (also known as post-foaming gels). U.S. Pat. No. 5,451,396 discloses a post-foaming shave gel that includes a water soluble polymer, such as hydroxyethyl cellulose, as a gelling aid and benzyl alcohol to improve clarity and gel strength. Non-aerosol shaving preparations, both lathering and non-lathering, have been available for decades and come in a variety of forms including bars, sticks, creams, gels and lotions. U.S. Pat. No. 5,340,571 discloses a non-aerosol shaving composition in the form of a clear gel that includes, among other things, potassium myristate and potassium palmitate in a specified ratio and hydroxyethyl cellulose as a gelling aid. U.S. Pat. No. 4,963,352 discloses a non-aerosol shaving composition that includes glyoxal, urea, diethyleneglycol monoethyl ether, fatty acid, alkanolamine, and benzyl alcohol, wherein the alkanolamine to fatty acid ratio is about 1:2 to 1:3.
Generally, the various non-aerosol shaving compositions typically have one or more deficiencies. They can be difficult to deliver and apply to the face. For example, they may be runny, stringy or hard to spread. They can be difficult to lather. And they can be difficult to rinse from the face, hands and razor, particularly when they contain oils, gums, thickening agents or associative thickeners. It would be desirable to provide a non-aerosol shaving composition that did not have these deficiencies.
SUMMARY OF THE INVENTION
The present invention is directed to a non-aerosol shaving composition in the form of a gel, preferably a clear gel. The non-aerosol shaving gel comprises water, an alkanolamine soap, preferably a triethanolamine soap, and a solubilizing agent for the soap, wherein the soap is completely dissolved in the water and the amount of soap and solubilizing agent is sufficient to provide the soap in the hexagonal liquid crystal phase in the composition. The present invention is also directed to an improved shaving method in which a shaving composition of the present invention is applied to an area of skin, then said area is shaved, preferably with a wet razor.
DETAILED DESCRIPTION OF THE INVENTION
The non-aerosol shaving composition of the present invention is in the form of a gel, preferably a clear gel. At a minimum, the shaving gel will include water, an alkanolamine soap, preferably a triethanolamine soap, and a solubilizing agent for the soap. The soap must be completely dissolved in the water and the amount of soap and solubilizing agent must be adjusted to a level sufficient to provide the soap in the hexagonal liquid crystal phase in the composition. When the soap is in the hexagonal liquid crystal form, the shaving composition becomes a stable gel instead of a runny liquid without the need for added thickening or gelling agents. This gel form facilitates ease of application because it will not run off the hands or face and spreads easily. This gel form also facilitates ease of rinsing because the addition of water readily transforms the composition to a less viscous soap phase form. For this reason, the composition preferably will be substantially free of other thickening or gelling agents such as gums, hydroxyalkyl celluloses, polyallyl sucrose copolymers, etc.
The shaving composition will typically comprise, by weight, in addition to water, about 18% to about 28%, preferably about 20% to about 27%, more preferably about 23% to about 26%, of the alkanolamine soap, and about 0.5% to about 6%, preferably about 1% to about 5%, more preferably about 1% to about 3%, solubilizing agent for the soap. As stated previously, the amount of soap and solubilizing agent must be adjusted to a level sufficient to provide the soap in the hexagonal liquid crystal phase in the composition.
Hexagonal liquid crystal phase is a well known concept in surfactant chemistry and means that the soap molecules are arranged in cylinders of indefinite length packed hexagonally in the aqueous continuous phase. This form can be readily seen with a phase contrast, polarizing microscope at magnifications of about 150-200×. When the soap molecules are arranged in this form, the composition becomes a non-flowing gel with a yield viscosity.
The alkanolamine soap may be pre-formed or, more typically, may be prepared in situ. It is prepared by the neutralization of a fatty acid (or a mixture of fatty acids) with an alkanolamine. The amount of fatty acid will range from about 12% to about 18%, preferably about 14% to about 16%. The amount of alkanolamine will be sufficient (typically a slight molar excess) to completely neutralize the fatty acid so that there is essentially no free fatty acid. Thus, the amount of alkanolamine will fall within the range of about 7.9% to about 11.9%, preferably about 8.8% to about 10.5%. Typically the composition will have a pH between about 7 and about 8.5, more typically between about 7.2 and about 8.0. Fatty acids which may be used include the C
10
to C
20
, preferably C
12
to C
18
, more preferably C
14
to C
16
, fatty acids. Typical fatty acids include lauric, oleic, coconut oil, myristic, palmitic and stearic acid and mixtures thereof. The preferred fatty acids are myristic and palmitic and mixtures thereof, with myristic being most preferred. Generally, the higher carbon chain fatty acids, such as stearic acid, are somewhat less preferred because their soaps are less soluble and require higher amounts of the solubilizing agent. The alkanolamine may be any suitable mono-, di- or tri-alkanolamine having from 2 to 6 carbon atoms in the alkanol chain(s). Preferably the alkanolamine will be monoethanolamine, diethanolamine or triethanolamine, with triethanolamine being most preferred.
The solubilizing agent is a material which helps to solubilize the soap component in water and assists in the formation and stability of the hexagonal crystal phase. The solubilizing agent is a bipolar molecule with a hydrophobic hydrocarbon tail, such as a benzyl or phenyl or medium alkyl moiety, and a non-ionic hydrophilic head, such as hydroxyl (—OH), glycol, or carboxylate. Typical solubilizing agents may include, for example, benzyl alcohol, phenoxyethanol, benzyl glycol, phenethyl alcohol, benzyl acetate, benzyl butyrate, benzyl glycoate, 2-ethylhexyl salicylate, 2-phenoxypropanol, 1-butanol, pentanol, hexanol, heptanol, octanol, hexylene glycol, butoxyethanol, butoxyisopropanol, butoxyethanol acetate, nonoxynols, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, alkylphenol ethoxylates, and mixtures thereof. The preferred solubilizing agent is selected from benzyl alcohol, hexylene glycol, phenoxyethanol, butoxyisopropanol and mixtures of at least two of these, with benzyl alcohol being most preferred. The amount of solubilizing agent should be sufficient to solubilize the soap component and allow it to form the hexagonal crystal phase. Typically it will comprise about 0.5% to about 6%, preferably about 1% to about 4%, more preferably about 1% to about 3%, of the composition.
Although not necessary to forming a useful shaving composition, other cosmetic ingredients may be advantageously added to improve the application aesthetics and/or achieve other shave benefits. For example, the composition may include one or more of the following components: beard wetting agents (e.g., non-ionic and/or anionic surfactants), skin conditioning agents (e.g., vitamins A, C and E, aloe, allantoin, panthenol, alpha-hydroxy acids, phospholipids, triglycerides, botanical oils, amino acids), cleansing agents, lathering agents, foam boosters, emollients, humectants (e.g., glycerin, sorbitol, propylene glycol), lubricants, fragrances, coloran
Dodd Kenneth T.
Kumar Promod
Stoner Karla Leum
Tang Jiansheng
The Gillette Company
Venkat Jyothsna
Williams Stephan P.
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