NO.sub.x sensor and method of measuring NO.sub.x

Measuring and testing – Gas analysis – Gas of combustion

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G01N 27419, G01N 2746

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active

058774068

ABSTRACT:
Disclosed is a NOx sensor and a method of measuring NOx capable of obtaining a large change in signal to measure a concentration of low concentration NOx in a measurement gas continuously and accurately with good response over a long period of time. A NOx sensor comprises a first internal space into which the measurement gas is introduced through a first diffusion rate-determining passage, a second internal space arranged with a NOx-reducing catalyst, into which an atmosphere is introduced through a second diffusion rate-determining passage, an electrochemical pumping cell for controlling a partial pressure of oxygen in the internal space by using a first oxygen ion-conductive solid electrolyte and electro-chemical cells provided in contact therewith, a partial oxygen pressure-detecting means for detecting the partial pressure of oxygen in the internal space by using the first oxygen ion-conductive solid electrolyte and electro-chemical cells provided in contact therewith, a first electrochemical sensor cell for outputting an electromotive force corresponding to the partial pressure of oxygen in the internal space, and a voltage-detecting means for detecting the electromotive force outputted from the first electrochemical sensor cell. The NOx concentration is determined from a value of the electromotive force of the first electrochemical sensor cell detected by the voltage-detecting means.

REFERENCES:
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patent: 5145566 (1992-09-01), Logothetis et al.
patent: 5217588 (1993-06-01), Wang et al.
patent: 5397442 (1995-03-01), Wachsman
patent: 5476001 (1995-12-01), Hoetzel et al.
patent: 5493896 (1996-02-01), Riegel
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Patent Abstract of Japan, vol. 017, No. 231, May 11, 1993 and JP -A-04 359144 (Mitsubishi motors Corp.), Dec. 11, 1992, abstract.

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