No reduction using sublimination of cyanuric acid

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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B01D 5334

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active

055187021

ABSTRACT:
A method of reducing the NO content of a gas stream comprises contacting the gas stream with an amount of HNCO at a temperature effective for heat-induced decomposition of cyanuric acid, said amount and temperature being effective for the resultant lowering of the NO content of the gas stream, said cyanuric acid being particulate and having a particle size of less than 90 .mu.m.

REFERENCES:
patent: 4731231 (1988-03-01), Perry
patent: 4731233 (1988-03-01), Thompson et al.
patent: 4851201 (1989-07-01), Heap et al.
patent: 4861566 (1989-08-01), Heap et al.
Back et al., "Photolysis of HNCO Vapor in the Presence of NO and O.sub.2 " Canadian Journal of Chemistry, vol. 46, 1968, pp. 531-534 (no month).
Perry, "Kinetics of the Reactions of NCO radicals with H.sub.2 and NO using Laser Photolysis-Laser Induced Fluoresence", Journal of Chemical Physics, vol. 82, 1985, p. 5485 (no month).
Caton et al. "Comparison of Nitric Oxide Removal by Cyanuric Acid And by Ammonia" Nov. 1988, p. 12.
Hawley, Gessner, ed. The Condensed Chemical Dictionary, 1981 p. 777 (no month).
Sarv et al., "Technical Paper: NO.sub.x reduction in an industrial-scale boiler by injecting cyanuric acid powder," 1989 Fall Meeting of the Western States Section/The Combustion Institute, Livermore, CA, Oct. 23-24, 1989, p. 14.
Smith, Chemical Engineering Kinetics, 1981 (no month) p. 638.
Pery et al. "Rapid Reduction of Nitrogen Oxides in Exhaust Gas Streams"; Nature 324; Dec. 18/25, 1986 pp. 657-658.

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