NMR measurement method and apparatus utilizing nyquist...

Electricity: measuring and testing – Particle precession resonance – Using a nuclear resonance spectrometer system

Reexamination Certificate

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Reexamination Certificate

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11330207

ABSTRACT:
In an NMR measurement method using an NMR apparatus which converts a received signal to digital data using an analog/digital converter and performs a spectral analysis, a folding and aliasing count is decided from a variation in a peak frequency and frequency discrimination is performed. More specifically, a Nyquist frequency is changed to cause a variation of the peak frequency. Since the Nyquist frequency is inversely proportional to an increment of an evolution time t1which is a feature of multi-dimensional NMR, the Nyquist frequency can be changed by changing the increment of the evolution time. Furthermore, the Nyquist frequency is changed in such a way that a ratio between different Nyquist frequencies is not a ratio between natural numbers n1and n2which are greater than 0 and smaller than or equal to the maximum folding and aliasing count.

REFERENCES:
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patent: 6213956 (2001-04-01), Lawton
patent: 7106478 (2006-09-01), Takano
patent: 2006-138666 (2006-06-01), None
Removal of F1 baseline distortion and optimization of folding in multidimensional NMR spectra, Journal and Magnetic Resonance, vol. 91, pp. 174-178 (1991).
Chapter 4, Multidimensional NMR spectroscopy, pp. 227-236 (Academic Press, 1995).

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