Nitroxide compounds for minimizing scorch in crosslinkable...

Details Nitroxide compounds for minimizing scorch in crosslinkable... Nitroxide compounds for minimizing scorch in crosslinkable...

2006-10-09

2008-12-16

Choi, Ling-Siu (Department: 1796)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

C525S387000, C525S375000, C525S330900

Reexamination Certificate

active

07465769

ABSTRACT:
Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

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