Nitrosochlorination of cyclo-olefins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 8100

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039313433

ABSTRACT:
Cyclo-olefins are converted in high yield to the corresponding chloro-nitroso dimers by dissolving the cyclo-olefin in liquid SO.sub.2 and contacting with NOCl while maintaining a substantially oxygen-free environment. Even higher yields are attained by controlling the gradual addition of the NOCl and by using a molar ratio of NOCl to cyclo-olefin of less than about 0.92:1.

REFERENCES:
patent: 2485180 (1949-10-01), Allison
patent: 3714255 (1973-01-01), Olechowski

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