Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1978-02-23
1979-04-10
Rollins, Alton D.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2605705P, 2605706, 260583CC, 260577, 260583DD, 260584R, 424325, 424330, 424269, C07C11100, C07D24904, C07D24906
Patent
active
041488032
ABSTRACT:
The product prepared by the process consisting of the steps of (a) reacting a nitroalcohol of the formula ##STR1## where R and R.sup.1 can be hydrogen, methyl, ethyl or hydroxymethyl in about a 1:1 mole ratio with an alkylamine represented by the formula R.sup.2 NH.sub.2 where R.sup.2 is alkyl of from 1 to 4 or more carbon atoms or phenyl, benzyl, toluyl, or xylyl at about 50.degree.-70.degree. thereby effecting formation of a nitroalkylamine; (b) reacting the nitroalkylamine with nitrous acid at about 0.degree.-5.degree., thereby forming a nitroso compound; and (c) reducing the nitroso compound.
REFERENCES:
patent: 2954314 (1960-09-01), Metzger et al.
patent: 3182086 (1965-05-01), Levering et al.
patent: 3256147 (1966-06-01), Meiser et al.
patent: 4013580 (1977-03-01), Hayashi et al.
patent: 4079063 (1978-03-01), Lind et al.
Dewey Robert H.
International Minerals & Chemical Corp.
Post Howard E.
Rollins Alton D.
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