Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1998-11-13
2000-11-14
Wu, David W.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526134, 526159, 526160, 526161, 526943, 502103, 502152, C08F 444, C08F 452
Patent
active
061471739
ABSTRACT:
This description addresses a process for the preparation of polyolefins from one or more olefinic monomers comprising combining said olefins under olefin polymerization conditions with an organometallic catalyst compound that is activated for olefin polymerization by reaction with a Group 13 element cocatalyst complex comprising at least one halogenated, nitrogen-containing aromatic group ligand. High number-average molecular weight polymers and copolymers at high rates of productivity were observed from the use of metallocene catalysts complexes when activated with [(C.sub.6 H.sub.5).sub.3 C][(C.sub.6 F.sub.5).sub.3 B(C.sub.5 F.sub.4 N)].
REFERENCES:
patent: 5198401 (1993-03-01), Turner et al.
patent: 5288677 (1994-02-01), Chung et al.
patent: 5427991 (1995-06-01), Turner
patent: 5643847 (1997-07-01), Walzer, Jr.
patent: 5854166 (1998-12-01), Marks et al.
Allcock, et al.,Synthesis, Reactivity, and the Electronic Structures of Fluoro- and Hydridophosphazene Anions: X-ray Crystal Structure of [Li(THF).sub.3 ][N.sub.3 P.sub.3 F.sub.2 H(BEt.sub.3)(n-C.sub.5 H.sub.4).sub.2 Fe].sup.1, Organometallics, (1991), 10(9), pp. 3090-3098.
Naumann, et al.,Preparation and Properties of New Tris(fluoroary)boranesI, Z. Anorg. Alleg. Chem. (1992), 618, pp. 74-76.
Marks, et al, J. Am. Chem. Soc. 1991 vol. 113, pp. 3623-3625.
Baird, Michael C., et al, J. Am. Chem. Soc., 1994, vol. 116, pp. 6435-6436.
"Darstellung und Eigenshafen neuer Tris(fluoraryl)borane," D. Nauman, et al, Zeitshrift fur anorganishe und allegemeine Chemie, 618 (1992) pp. 74-76.
"Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic, Structural, Solution Dynamic, and Polymerization Catalytic Study," Yang, et al, J.Am. Chem. Soc., vol. 116, 1994, pp. 1001-10031.
James C. W. Chien, Jour. Poly. Sci.: Pt A: Poly, Chem. vol. 29, (1991) 1603-1607.
"Synthesis, reactivity, and the electronic structures of fluoro-and hydridophosphazene anions: x-ray crystal structure of [Li(THF).sub.3 ]N.sub.3 P.sub.3 F.sub.2 H(Bet.sub.3)(.eta.-C.sub.5 H.sub.4).sub.2 Fe.sup.1, "Harry R. Allcock, et al, Organometallics (1991) vol. 10 (9), pp.1090-1098.
Jones Lisa Kimes
Lu Caixia
Sher Jaimes
Univation Technologies LLC
Wu David W.
LandOfFree
Nitrogen-containing group 13 anionic complexes for olefin polyme does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Nitrogen-containing group 13 anionic complexes for olefin polyme, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Nitrogen-containing group 13 anionic complexes for olefin polyme will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2066256