Nitrogen-containing aromatic heterocyclic ligand-metal complexes

Details Nitrogen-containing aromatic heterocyclic ligand-metal complexes Nitrogen-containing aromatic heterocyclic ligand-metal complexes

1990-08-24

1992-09-22

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568311, 568385, 568815, 568818, 568822, 568910, 568320, 568360, 568399, 568401, 568431, 568400, C07C 4528

Patent

active

051498804

ABSTRACT:
Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxgen are disclosed. Processes whereby activated hydrogen peroxide or dioxygen are used to transform various organic substrates are also disclosed. In particular, processes for the conversion of methylenic carbons to carbonyls, for the dioxygenation of aryl olefins, acetylenes and aryl-.alpha.-diols, for the oxidation of alcohols and aldehydes and for the removal of mercaptans from gaseous streams and for the removal of hydrogen sulfide and/or mercaptans from liquid streams are disclosed.

REFERENCES:
patent: 4028423 (1977-06-01), Brawnstein et al.
patent: 4259527 (1981-03-01), Maus et al.
patent: 4341907 (1982-07-01), Zelonka
patent: 4482746 (1984-11-01), Humolin
patent: 4659829 (1987-04-01), Saussine et al.
patent: 4978799 (1990-12-01), Sanderson et al.

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