Nitroaliphatic difluoroformals

Details Nitroaliphatic difluoroformals Nitroaliphatic difluoroformals

1975-12-16

1978-10-17

Miller, Edward A.

Explosive and thermic compositions or charges

Containing nitrated organic compound

260615A, 260615F, C06B 2500, C07C 4304

Patent

active

041207106

ABSTRACT:
Nitroaliphatic difluoroformals of the formula RCH.sub.2 OCF.sub.2 OCH.sub.2 R' wherein R = FC(NO.sub.2).sub.2 -- and R' = F.sub.2 C(NO.sub.2)-- or CF.sub.3 --; or R = R' = CF.sub.3 OCH.sub.2 C(NO.sub.2).sub.2 --. The compounds are prepared in accordance with the following reaction: ##STR1## carried out at temperatures of from about 95.degree. C to about 150.degree. C. The compounds are especially useful as energetic plasticizers in explosive compositions.

REFERENCES:
patent: 3388147 (1968-06-01), Kamlet et al.
patent: 3396187 (1968-08-01), Benzinger et al.
patent: 3922311 (1975-11-01), Peters
patent: 3962349 (1976-06-01), Adolph
Aldrich et al., J. Org. Chem., 29, 11-15 (1964).
Shipp et al., J. Org. Chem., 31, 853-856 (1966).

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