Nitration process for the preparation of 2,6-dialkylaniline

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564305, 564419, 564437, C07C 8511

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active

043407587

ABSTRACT:
A process for the preparation of 2,6-dialkylaniline which comprises the reaction of 1,3-dialkylbenzene with isobutene in the presence of a hydrogen fluoride catalyst to form 1,3-dialkyl-5-tertiary-butylbenzene, which is subsequently nitrated in the presence of a soluble mercuric salt catalyst to form 2-nitro-1,3-dialkyl-5-tertiary-butylbenzene, which is then catalytically hydrogenated to give 2,6-dialkyl-4-tertiary-butylaniline, followed by pyrolysis in the presence of a heterogeneous acidic catalyst.

REFERENCES:
patent: 3123644 (1964-03-01), Olin
patent: 3483266 (1969-12-01), Hill

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