Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1983-04-28
1985-01-29
Sebastian, Leland A.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
260466, 260467, 568924, 568943, C07C 7902
Patent
active
044967837
ABSTRACT:
Nitration of organic compounds and organic nitrogen compounds produced.
Organic nitrogen compounds are formed in the vapor phase by organic radical formation by reaction of an organic compound with hydroxyl radicals derived from the reaction between hydrogen peroxide and nitrogen dioxide and the nitration of the organic radicals, suitably with nitrogen dioxide. The process may be conducted as a single stage process using an excess of nitrogen dioxide over that required for hydroxyl radical formation. The production of hydroxyl radicals is maximized by the use of a catalytic solid surface such as a solid acid or an acidic oxide or mixed oxide. The product may be a mixture of some or all of the nitrite, nitrate and nitro-derivative which may be used as such, e.g. as a fuel additive, as a source of the individual compounds or as a feedstock for a further synthesis.
REFERENCES:
patent: 3966411 (1976-06-01), Ross
Urbanski, Chemistry and Technology of Explosives, vol. 1, The MacMillan Co., New York, 1964, pp. 120, 121, 136 and 137.
Audley Gary J.
Baulch Donald L.
Campbell Ian M.
Interox Chemicals Limited
Sebastian Leland A.
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