Nitration of organic compounds

Details Nitration of organic compounds Nitration of organic compounds

1983-04-28

1984-12-11

Sebastian, Leland A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

260466, 260467, 568924, 568947, C07C 7602

Patent

active

044879881

ABSTRACT:
Organic nitrogen compounds are formed in the vapor phase by organic radical formation by reaction of an organic compound, suitably an alkane, with hydroxyl radicals derived from the reaction between hydrogen peroxide and nitrogen dioxide and the nitration of the organic radicals, suitably with nitrogen dioxide. The process is conducted using a molecular oxygen additive which directs the reaction towards the formation of the nitrate corresponding to the organic compound which may predominate in the organic reaction products.

REFERENCES:
patent: 3966411 (1976-06-01), Ross et al.
patent: 4329522 (1982-05-01), Gilbert et al.
Urbanski, Chemistry and Technology of Explosives, vol. I, The MacMillan Co., New York, 1964, pp. 120, 121, 136 and 137, (TP 270 U7).

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