Nickel-phosphorus oxidative dehydrogenation catalyst

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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260680E, 2606833, B01J 2718, C07C 548

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active

039430685

ABSTRACT:
Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase at an elevated temperature in the presence of an oxygen-containing gas with a catalyst containing nickel in combination with phosphorus and oxygen. The nickel-phosphorus-oxygen catalysts are particularly characterized in that they contain from 0.1 to 16.8 weight percent phosphorus, based on the weight of the nickel-phosphorus-oxygen catalyst. Representative of such conversions is the oxidative dehydrogenation of butane to 1,3-butadiene. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.

REFERENCES:
patent: 2926207 (1960-02-01), Folkins et al.
patent: 3268611 (1966-08-01), Bajars
patent: 3270080 (1966-08-01), Christmann
patent: 3308188 (1967-03-01), Bajars
patent: 3538019 (1970-11-01), Capik et al.
Hayek et al., Chemical Abstracts, Vol. 54, 10440 (1960).

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