Nickel hypophosphite manufacture

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing inorganic compound

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C25B 100

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active

055229727

ABSTRACT:
A method for preparing nickel hypophosphite by contacting a nickel anode with a solution of hypophosphite anions and applying a current through the anode to a counter-electrode in contact with the solution to anodically dissolve the nickel of the anode into the hypophosphite solution, thereby forming a nickel hypophosphite solution. A one-compartment electrolysis cell and a three-or-more-compartment electrodialysis cell embodying the method of the invention are described.

REFERENCES:
patent: 5225052 (1993-07-01), Takikawa
Metal Finishing Handbook, Metals & Plastics Pub. Inc. (1987) (month not available).
Chem. Abs. vol. 76, 1972, 47867x, "Nickel(II) hypophosphite". Svehla, Pavel, Czech. 139,245, 15 Dec. 1970.
Chem. Abs., vol. 81, 1974, 172399a, "Nickel hypophosphite with a low iron content". Svehla, Pavel, Czech. 152,901, 15 Apr. 1974.
Tsaka et al., Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 45(6), 380-5 (1977) month not available.
Hongyu et al., "Electrolytic Regeneration of Electroless Nickel (Ni) Solution," Electroplating & Polution Control, vol. 13, No. 2, Mar. 1993 (with translation).

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