Ni catalyst, process for making catalysts and selective...

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Hydrocarbon is contaminant in desired hydrocarbon

Reexamination Certificate

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C585S258000, C585S260000, C585S262000

Reexamination Certificate

active

07408089

ABSTRACT:
More selective and efficient Ni hydrotreating catalysts are those which contain more than about 60% of the Ni content on the peripheral surface of porous supports, such as extruded alumina, which may be obtained by spraying an atomized solution of a Ni compound onto the support and drying it at a temperature in the range of from 200 to 600° C. When used, for example, to remove acetylenic compounds from butadiene streams, higher recovery of the desired butadiene with lower acetylenic content and low heavy polymer deposition is obtained than was possible with prior catalysts.

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Howard F. Rase, Heterogeneous Catalysts, Handbook of Commercial Catalysts, Chapter 12, Hydrogenation, pp. 105-139, 1998.

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