NI-based FTM shadow masks having a nickel phosphide black layer

Electric lamp and discharge devices – Cathode ray tube – Shadow mask – support or shield

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148254, H01J 2907

Patent

active

049298640

ABSTRACT:
The power handling capacity of nickel-iron-based flat tensioned foil shadow masks for flat faceplate cathode ray tubes (CRTs) is enhanced by providing the flat tensioned mask (FTM) with a thin surface layer which is enriched in nickel, which is converted to a nickel phosphide compound. The nickel phosphide surface layer is formed on the mask by immersing the mask in a first bath of a strong reducing acid followed by immersing the mask in a second strong reducing acid having an effective amount of hypophosphite ion. The thin surface layer of a nickel phosphide compound increases the FTM emissivity and reduces FTM color impurity at high electron beam energies. The nickel phosphide compound may be stabilized in the frit-lehr cycle during CRT assembly or in a separate heating operation.

REFERENCES:
patent: 3867207 (1975-02-01), Decker et al.
patent: 3967985 (1976-07-01), Izumi et al.
patent: 4695761 (1987-09-01), Fendley
Patent Abstracts of Japan, No. 58-197635 having the publication date 11-17-83 (1984).

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