New vinyl monomers capable of forming side-chain liquid crystall

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560 41, 560145, 560172, 562449, 562450, 562574, G09F 500

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active

047939494

ABSTRACT:
There is disclosed a new vinyl monomer capable of forming polymeric vesicles, micelles, monolayers, and side-chain liquid crystalline polymers. The vinyl monomer is of the formula ##STR1## wherein R.sub.1 is substituted or unsubstituted long chain alkyl or aryl and R.sub.2 is a hydrogen atom, alkyl, or aryl.
The side-chain liquid crystalline polymers can be formed by free radical polymerization or by anionic polymerizations techniques. The different reaction methods give polymers of different configuration; the anionic technique results in a polymer having a nitrogen atom in the backbone. The polymers are useful in film and fiber formation and display good toughness.

REFERENCES:
patent: 2622074 (1952-12-01), Coover, Jr. et al.
patent: 4634775 (1987-01-01), Beck et al.
Gallina et al., Synthesis of 2-Alkoxy-2-Acylaminopropionic Acids by Alkoxymercuration-Demercuration of 2-Acylaminoacrylic Acids, Journal of the Chemical Society, Perkin Transactions I, Organic and Bio-Organic Chemistry, vol. 10, pp. 1134-1136, (1973).

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