New supported polymerization catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502113, 502120, 502132, 502117, 526114, 526116, 526119, 526352, C08F 4646, C08F 4648, C08F 1002

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active

050772554

ABSTRACT:
An olefin polymerization supported catalyst comprising the supported reaction product of at least one metallocene of a metal of Group IVB, VB, and VIB of the Periodic Table, a non-metallocene transition metal containing compound of a Group IBV, VB, or VIB metal and an alumoxane, said reaction product formed in the presence of the support. The supported product is highly useful for the polymerization of olefins especially ethylene and especially for the copolymerization of ethylene and other mono and diolefins.

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James C. W. Chien, "Reduction in Ti(IV)Alkyls in Cab-O-Sils Surfaces", Journal of Catalysis, 23, 71 (1971).
Dag Slotfeldt-Ellingsene et al., "Heterogenization of Homogeneous Catalysts", Journal of Molecular Catalysis, 9, 423 (1980).

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