Negative active material for lithium rechargeable batteries...

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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Details

C429S218100, C429S231600, C427S113000, C427S126300

Reexamination Certificate

active

10160204

ABSTRACT:
The present invention relates to a negative active material for a lithium rechargeable battery and a method of preparing the same, and the negative active material prepared by coating a carbon source with a coating liquid, and drying the carbon source, and the negative active material comprises a core having a carbon source with surface-treatment layer formed on the surface of the core, the surface-treatment layer having at least one compound of coating element selected from the group cosnsisting of amorphous, semi crystalline, or crystalline hydroxides, oxyhydroxides, oxycarbonates, and hydroxidecarbonates.The present invention provides a negative active material coated with a surface-treatment layer of a coating-element-included hydroxide, a coating-element-included oxyhydroxide, a coating-element-included oxycarbonate, or a coating-element-included hydroxycarbonate, and thereby a battery having the negative active material has less change in thickness after expansion of the active material, that is, from 12.2% to 5.3%, and furthermore, cycle-life characteristics are improved (7% or more improvement at the 200th cycle) and voltage characteristics are improved (0.04 V or more improvement at the 200th cycle).

REFERENCES:
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patent: 5200282 (1993-04-01), Ohnishi et al.
patent: 6096454 (2000-08-01), Tran et al.
patent: 6391495 (2002-05-01), Choi et al.
patent: 1254961 (2000-05-01), None
patent: 64-59766 (1989-03-01), None
patent: 11-120992 (1999-04-01), None
patent: 2001-85003 (2001-03-01), None
patent: 2002-124262 (2002-04-01), None
Patent Abstract of Japan, Publication No. 11-120992, Published on Apr. 30, 1999, in the name of Inoue Tomohiro, same as above.

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