Near infrared fluorescent security thermal transfer printing...

Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor

Reexamination Certificate

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Details

C156S238000, C427S256000, C428S195100, C428S484100, C428S488110, C428S690000, C428S913000, C428S914000

Reexamination Certificate

active

06174400

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to thermal transfer printing media containing near-infrared fluorophores (NIRFS) which may be monomeric, copolymerized or admixed into a carrier polymer/polymer backbone which is incorporated into the wax/thermoplastic resin which forms the thermally meltable ink layer (or printing media layer) on the thermal transfer ribbon.
BACKGROUND OF THE INVENTION
Thermal transfer printing media and the ribbons used for thermal transfer are well known in the art, Generally the ribbon comprises at least three main layers, a thermally meltable ink layer, a polymer film layer and a heat resistant polymer layer. The compositions of the various layers are described in JP A 3-79,683, (Apr. 4, 1991). However, thermal transfer media or ribbons capable of printing invisible marks are not disclosed.
Thermal transfer ribbons incorporating visible fluorescent dyes or pigments are disclosed in U.S. Pat. Nos. 4,627,997, 4,657,697,4,816,344, 5,089,350 and 5,552,231. Ribbons containing marking compositions, which are invisible to the human eye, are not disclosed.
Thermal transfer ribbons incorporating invisible UV dyes or pigments and visible pigments are disclosed in U.S. Pat. No. 5,516,590. However, thermal transfer ribbons incorporating invisible marking compound which are not visible to the unaided human eye, and particularly invisible near infrared fluorescent compounds are not disclosed.
SUMMARY OF THE INVENTION
The present invention relates to thermal transfer ribbons comprising a ribbon backing element and at least one printing media layer comprising at least one near infrared fluorescent compound in a concentration which provides detectable fluorescence without imparting color to a mark made from said printing media layer.
The present invention further relates to preparation of printing and marking ribbons consisting of thin film elements with printing media adhered to one side thereof.
Also disclosed is a method for applying a mark comprising at least one invisible near infrared fluorescent compound said method comprising the steps of providing a thermal transfer ribbon comprising a ribbon backing element having coated on one side at least one printing media layer comprising at least one invisible NIRF compound; and contacting the non-coated side of said ribbon backing element with a heating element so as to contact said printing media layer with a print receiving media under conditions sufficient to thermally transfer an image to said print receiving media.
Also disclosed is a method for detecting a thermal transfer mark comprising at least one invisible NIRF compound wherein said method comprises the steps of exciting said at least one invisible NIRF compound having a peak absorbance with radiation focused within 10 nm of said peak absorbance; and detecting fluorescence emitted from said invisible NIRF compound.


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