Natural gas conversion to higher hydrocarbons

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses

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Details

585638, 585733, 518702, 518711, C07C 110

Patent

active

057146578

ABSTRACT:
This patent is concerned with a unique process for converting natural gas into hydrocarbons. More particularly, it concerns a novel combination of processing steps wherein the natural gas is first converted into syn gas, the hydrogen of which is reacted with carbon dioxide to produce a mixture of water and carbon monoxide which is then contacted with a metal catalyst to give a mixture of hydrocarbons.

REFERENCES:
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patent: 2472219 (1949-06-01), Lyons
patent: 2579663 (1951-12-01), Gilbert et al.
patent: 2786863 (1957-03-01), Kolbel et al.
patent: 3723344 (1973-03-01), Reynolds
patent: 4690695 (1987-09-01), Doshi
patent: 4704487 (1987-11-01), Devries et al.
patent: 4704488 (1987-11-01), Devries et al.
patent: 4704493 (1987-11-01), Devries et al.
patent: 4836833 (1989-06-01), Nicholas et al.
Green et al., "Conversion of Natural Gas to Transport Fuels," Tecnol. Clencia. Ed. (1991) 7:25-37.
Fox et al., "An Evaluation of Direct Methane Conversion Processes," Chemical Engineering Progress (1990) Apr.: 42-50.
Taylor & Noceti, "Conversion of Methane to Gasoline-Range Hydrocarbons," Proc. 9th Int'l Cong. on Catal. (1988) 11: 990-997.
Scurrell, "Prospects for the Direct Conversion of Light Alkanes to Petrochemical Feedstocks and Liquid Fuels," Applied Catalysis (1987) 32: 1-22.
Keim, "C, Chemistry: Potential and Developments," Pure & Applied Chem. (1986) 825-832.
Montgomery et al., "Thermodynamics and Stoichiometry of Synthesis Gas Production," Industrial & Engineering Chemistry (1948) Apr.: 601-607.
Schwob, "Fabrication du Methanol. La retroconversion du gaz carbonique, filiere d'avenir," L'Actualite Chimique (1982) Jan.: 28-30. The non-catalytic, high temperature Reverse Water Gas Shift reaction described herein is also described in U.S. Patent No. 3,723,344.
Kolbel & Vorwerk, "Synthese von Kohlenwasserstoffen aus Kohlenoxyd und Wasserdampf," Brennstoff-Chemie (1957) 38:2-9. The catalytic process described herein is also described in U.S. Patent. No. 2,579,663 and 2,786,683.

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