Natural gas conversion

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce unsaturate

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585500, 585656, C07C 100

Patent

active

045337802

ABSTRACT:
A method of synthesizing hydrocarbons from a methane source which includes the steps of separating a mixture of lower alkanes to form a first fraction containing predominately methane and at least one second fraction containing predominately C.sub.2 + alkanes; dehydrogenating the second C.sub.2 + fraction to form an effluent comprising C.sub.2 + olefins; contacting the methane fraction with an oxide of a metal which oxide when contacted with methane at between about 500.degree. and 1000.degree. C. is reduced and produces higher hydrocarbon products and water; and oligomerizing the C.sub.2 + olefin fraction and the methane contacting effluent to produce higher hydrocarbon products.

REFERENCES:
patent: 4293722 (1981-10-01), Ward et al.
patent: 4443644 (1984-04-01), Jones et al.

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