Nanostructured titanium monoboride monolithic material and...

Compositions – Electrically conductive or emissive compositions – Metal compound containing

Reexamination Certificate

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C252S500000, C252S520200, C089S036020, C148S022000, C148S027000, C501S095300, C501S096300, C419S012000, C419S048000, C075S244000, C423S297000

Reexamination Certificate

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07459105

ABSTRACT:
A nanostructured monolithic titanium boride (TiB) material and methods of forming such a material are disclosed and described. This material has a room-temperature four-point flexural strength about three times that of commercially available titanium diboride (TiB2). The achievement of nanostructured internal microstructural arrangement having a network of interconnected titanium monoboride whiskers affords a very high strength to this material above some of the best ceramic materials available in the market. The material contains a small amount of titanium, but it is largely made of TiB phase with substantially no TiB2. The nanostructured monolithic titanium boride material can be formed by high temperature processing of a powder precursor having carefully selected weight and size distributions of titanium and titanium diboride powders. Potential applications of this material can include wear resistant components such as die inserts for extrusion dies, nozzles, armor, electrodes for metal refining etc. An important advantage of TiB over other hard ceramics is that TiB can be cut by electro-discharge machining (EDM) without difficulty, unlike most ceramics.

REFERENCES:
patent: 3029162 (1962-04-01), Samuel et al.
patent: 3147543 (1964-09-01), Doerner et al.
patent: 3251719 (1966-05-01), Tepper et al.
patent: 3634145 (1972-01-01), Homan
patent: 3673005 (1972-06-01), Kunst
patent: 3676371 (1972-07-01), Zollner et al.
patent: 3787245 (1974-01-01), Kunst
patent: 3806374 (1974-04-01), Krzyminski
patent: 3809583 (1974-05-01), Krzyminski
patent: 3870569 (1975-03-01), Krzyminski
patent: 3936327 (1976-02-01), Fichtl et al.
patent: 3937619 (1976-02-01), Clougherty
patent: 3999954 (1976-12-01), Kolaska et al.
patent: 4011107 (1977-03-01), Hayes
patent: 4019873 (1977-04-01), Reiter
patent: 4040870 (1977-08-01), Holzl
patent: 4126488 (1978-11-01), Kunst et al.
patent: 4268582 (1981-05-01), Hale et al.
patent: 4289545 (1981-09-01), Thevenot et al.
patent: 4353885 (1982-10-01), Hoekje
patent: 4398968 (1983-08-01), Koyama et al.
patent: 4402764 (1983-09-01), Clark et al.
patent: 4404045 (1983-09-01), Thevenot et al.
patent: 4459328 (1984-07-01), Mizuhara
patent: 4528121 (1985-07-01), Matsushita et al.
patent: 4536224 (1985-08-01), Beyer et al.
patent: 4637837 (1987-01-01), von Matuschka et al.
patent: 4673550 (1987-06-01), Dallaire et al.
patent: 4692385 (1987-09-01), Johnson
patent: 4844949 (1989-07-01), Arai et al.
patent: 4857116 (1989-08-01), Allam et al.
patent: 4906430 (1990-03-01), Abkowitz et al.
patent: 4957421 (1990-09-01), Baldi
patent: 4968348 (1990-11-01), Abkowitz et al.
patent: 4971624 (1990-11-01), Clark et al.
patent: 5118026 (1992-06-01), Stacher
patent: 5158913 (1992-10-01), Saito et al.
patent: 5187128 (1993-02-01), White et al.
patent: 5296419 (1994-03-01), White et al.
patent: 5378327 (1995-01-01), Sekhar et al.
patent: 5399207 (1995-03-01), Kemp
patent: 5409518 (1995-04-01), Saito et al.
patent: 5455068 (1995-10-01), Aves et al.
patent: 5464699 (1995-11-01), Baldi
patent: 5573604 (1996-11-01), Gerdes
patent: 5620521 (1997-04-01), Tachikawa et al.
patent: 5702448 (1997-12-01), Buechel et al.
patent: 5745990 (1998-05-01), Lee et al.
patent: 5799238 (1998-08-01), Fisher, II et al.
patent: 5868796 (1999-02-01), Buechel et al.
patent: 5966585 (1999-10-01), Sue
patent: 6024915 (2000-02-01), Kume et al.
patent: 6245162 (2001-06-01), Baudis et al.
patent: 6287711 (2001-09-01), Nieh et al.
patent: 6306225 (2001-10-01), Hunger et al.
patent: 6428885 (2002-08-01), Seitz et al.
patent: 6458218 (2002-10-01), Savich
patent: 6478887 (2002-11-01), Sue et al.
patent: 6503344 (2003-01-01), Baudis et al.
patent: 6551371 (2003-04-01), Furuta et al.
patent: 6770358 (2004-08-01), Berger et al.
patent: 2001/0041230 (2001-11-01), Hunger et al.
patent: 2003/0047463 (2003-03-01), Ward-Close et al.
patent: 2003/0099762 (2003-05-01), Zhang et al.
patent: 2005/0208213 (2005-09-01), Chandran et al.
patent: 2006/0137517 (2006-06-01), Palicka et al.
patent: 686187 (1964-05-01), None
patent: 903676 (1962-08-01), None
patent: WO 2004/046262 (2004-06-01), None
Panda et al, “Synthesis of ductile Titanium-Titanium Monoboride (Ti-TiB) Composites with beta-Titanium Matrix: The nature of TiB formation and composition properties,” Metallurgical and Material Transactions, 2003, 34A, pp. 1371-1385.
Monolith, Webster Merriam Dictionary, 2008, pp. 1-3.
Aich, S. et al., “TiB Whisker Coating On Titanium Surfaces by Solid-State Diffusion: Synthesis, Microstructure, and Mechanical Properties”, Metallurgical and Materials Transactions A (2002) vol. 33A, pp. 3489-3498.
Fan, Z. et al., “The kinetics and mechanism of interfacial reaction in sigma fibre-reinforced Ti MMCs”, Composites Part A (1997) vol. 28A, pp. 131-140.
Hill, Michael R. et al. “Fracture Testing of a Layered Functionally Graded Material”Fracture Resistance Testing of Monolithic and Composite Brittle Materials, ASTM STP 1409, J.A. Salem, G.D. Quinn and M.G. Jenkins, Eds., American Society for Testing and Materials, 2002, West Conshohocken, PA.
Sahay, S.S. et al., “Evolution of microstructure and phases in in situ processed Ti-TiB composites containing high volume fractions of TiB whiskers”, J. Mater. Res. (Nov. 1999) vol. 14, No. 11, pp. 4214-4223.
Yang, Y.Q. et al., “TEM investigations of interfacial processes in SCS-6 SiC/TiB2/Super α2composites”, Composites: Part A (1999) vol. 30, pp. 1209-1214.
Alman, D.E. et al., “The Abrasive Wear of Sintered Titanium Matrix-Ceramic Particle Reinforced Composites”, Wear, 1999, vol. 225-229, pp. 629-639.
Banerjee, Rajarshi, “Laser Deposition of In Situ Ti-TiB Composites”, Advanced Engineering Materials, 2002, pp. 1-5, vol. 4, No. 11.
Jain, Vipin, et al. , Influence of the Pack Thickness of the Boronizing Mixture on the Boriding of Steel, Surface and Coatings Technology, 2002, pp. 21-26, vol. 149.
Kooi, B.J. et al., “The Evolution of Microstructure in a Laser Clad TiB-Ti Composite Coating”, Acta Materialia, 2003 ,pp. 831-845, vol. 51.
Matiasovsky, K. et al., “Electrochemical and Thermochemical Boriding in Molten Salts”, Surface and Coatings Technology, 1988, pp. 133-149, vol. 35.
Matuschka, Alfred Von Graf, “Boronizing”, Heyden & Son, Inc. Philadelphia, 1980, pp. 11-31.
Meric, Cevdet et al., “Investigation of the Effect on Boride Layer of Powder Particle Size Used in Boronizing with Solid Boron-Yielding Substances”, Materials Research Bulletin, 2000, pp. 2165-2172, vol. 35.
Sioshansi, Piran, “Improving the Properties of Titanium Alloys by Ion Implantation”, Applied Technology, Mar. 1990, pp. 1-2.
Sup Lee, Chang et al., “Improvement of Hardness and Wear Resistance of (TiC, TiB)/Ti-6A1-4V Surface-Alloyed Materials Fabricated by High-Energy Electron-Beam Irradiation, Metallurgical and Materials Transactions”, Jul. 2003, pp. vol. 34A.
Ueda, N. et al., “Boriding of Nickel by the Powder-Pack Method”, Surface and Coatings Technology, 2000, pp. 25-30, vol. 126.
Atri et al., “Elastic properties of in-situ processed Ti-TiB composites measure by impulse excitation of vibration,” Materials Science and Engineering, A, Structure Materials: properties microstructure and processing, 1999, V 271, No. 1-2, pp. 150-159, Abstract only.
Panda et al., “Titanium-Titanium Boride (Ti-TiB) Functionally Graded Materials through Reaction Sintering: Synthesis, Microstructure, and Properties,” Metallurgical and Materials Transactions, Sep. 2003, pp. 1993-2003, V 34A.

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