Nanostructured composite anode with nano gas channels and...

Chemistry: electrical current producing apparatus – product – and – Fuel cell – subcombination thereof – or method of making or... – Electrode structure or composition

Reexamination Certificate

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Reexamination Certificate

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08053142

ABSTRACT:
A nanostructured composite anode with nano gas channel and an atmosphere plasma spray manufacturing method thereof are disclosed. The anode consists of a porous base material and a composite film with nano gas channels above the porous base material while the composite film has a plurality of nano gas pores and a plurality of nano gas channels. The manufacturing method according to the present invention includes the steps of: provide micron-sized agglomerated and nanostructured powders having mixture of nano oxide particles and a binder; heat the micron-sized agglomerated and nanostructured powders into melt or semi-melt oxide mixture; spray the melt or semi-melt oxide mixture on a porous base material; and generate the nanostructured anode composite film with nano gas channels through hydrogen reduction. The anode of the present invention increases the electrochemical activity and slows down nickel particle aggregation effect under high temperature environment.

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Nanostructured NiO/YSZ powder, Plasma Spray Grade 2004.
Chen et al, air plasma spraying colloidial solutions of nanosized ceramic powders, 2004, journal of materials science, edition 39, pp. 4171-4176.
Keech et al, synthesis and performance of sol gel prepared ni-YSZ cermet SOFC anodes, Feb. 1, 2005, journal of electrocheical society, edition 152, pp. a645-a651.
Kek et al, electrical and microstructural investigations of cermet anode/YSZ thin film systems, 2001, journal of the european ceramic society, pp. 1861-1865.

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