Nanocomposite copper-ceria catalysts for low temperature or...

Tobacco – Smoke separator or treater – By chemical reaction – e.g. – ion-exchange – chelating,...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C131S331000, C131S341000, C131S342000, C131S364000, C131S365000, C131S360000

Reexamination Certificate

active

06857431

ABSTRACT:
Nanocomposite copper-ceria catalysts are provided, which comprise copper oxide nanoparticles, copper nanoparticles, or a mixture thereof combined with ceria nanoparticles. Methods for making such catalysts are also provided, which involve the steps of (i) combining ceria nanoparticles in an aqueous suspension with copper 2,4-pentanedionate to form a slurry; (ii) heating the slurry formed in step (i) under an inert gas atmosphere or an oxygen-argon atmosphere, at a temperature and for a time sufficient to cause decomposition of the copper 2,4-pentanedionate to form copper nanoparticles and/or copper oxide nanoparticles that are combined with the ceria nanoparticles; and (iii) optionally, subjecting the product formed in step (ii) to a heat treatment process under conditions effective to convert at least some of the copper nanoparticles to copper oxide nanoparticles. The nanocomposite copper-ceria catalysts are useful for low-temperature and near-ambient temperature catalysis, such as the oxidation of carbon monoxide, the reduction of nitric oxide and the conversion of hydrocarbons. The nanocomposite copper-ceria catalysts have a variety of potential applications, for example, in vehicle exhaust emission systems of automobiles and diesel engines, cold starting of automobile engine, fuel cells, lasers, hydrocarbon conversion reactors, air filters for the conversion of carbon monoxide and/or indoor volatile organic compounds, and smoking articles.

REFERENCES:
patent: 3272759 (1966-09-01), Stiles
patent: 3284370 (1966-11-01), Clifford et al.
patent: 3472237 (1969-10-01), Stephens
patent: 3819535 (1974-06-01), Huba et al.
patent: 4113658 (1978-09-01), Geus
patent: 4252687 (1981-02-01), Dale et al.
patent: 4256609 (1981-03-01), Dale et al.
patent: 4317460 (1982-03-01), Dale et al.
patent: 4426319 (1984-01-01), Blanchard et al.
patent: 4450245 (1984-05-01), Adair et al.
patent: 4639432 (1987-01-01), Holt et al.
patent: 4711773 (1987-12-01), Mesters et al.
patent: 4839146 (1989-06-01), Cho et al.
patent: 4940686 (1990-07-01), Tooley et al.
patent: 4943550 (1990-07-01), Kolts et al.
patent: 4956330 (1990-09-01), Elliott et al.
patent: 4968656 (1990-11-01), Fukuda et al.
patent: 4994247 (1991-02-01), Tooley et al.
patent: 4996180 (1991-02-01), Diwell et al.
patent: 5017357 (1991-05-01), Kolts et al.
patent: 5075276 (1991-12-01), Ozawa et al.
patent: 5258340 (1993-11-01), Augustine et al.
patent: 5499636 (1996-03-01), Baggett et al.
patent: 5666976 (1997-09-01), Adams et al.
patent: 5692525 (1997-12-01), Counts et al.
patent: 5692526 (1997-12-01), Adams et al.
patent: 5733837 (1998-03-01), Nakatsuji et al.
patent: 5905056 (1999-05-01), Hartweg et al.
patent: 5915387 (1999-06-01), Baggett et al.
patent: 5988176 (1999-11-01), Baggett et al.
patent: 5990040 (1999-11-01), Hu et al.
patent: 5993762 (1999-11-01), Rajaram et al.
patent: 6026820 (2000-02-01), Baggett et al.
patent: 6209547 (2001-04-01), Koller et al.
patent: 6306795 (2001-10-01), Ryan et al.
patent: 20020032349 (2002-03-01), Baker et al.
patent: 127609 (1919-06-01), None
patent: 609166 (1948-09-01), None
P. Bera et al., Ionic Dispersion of Pt & Pd on CeO2by Combustion Method: Effect of Metal-Ceria Interaction on Catalytic Activities for NO Reduction & CO and Hydrocarbon Oxidation, Journal of Catalysis 2000, vol. 196, pp. 293-301, Academic Press, USA.
T. Bueluesin et al., Studies of the Water-Gas-Shift Reaction on Ceria-Supported Pt, Pd, & Rh: Implications for Oxygen-Storage Properties, Applied Catalysis B. Environmental, 15, 1998, pp. 107-114, Elsevier Science B.V. , Oxford, United Kingdom.
M. Flytzani-Stephanopoulos, Nanostructured Cerium Oxide “Ecocatalysts”, MRS Bulletin, Nov. 2001, pp. 885-889.
Parthasarathi Bera et al., Studies on Cu/CeO2: A New NO Reduction Catalyst, Journal of Catalysis 186, 1999, pp. 36-44, Academic Press, USA.
Fu, et al., Nanostructured Au-CeO2Catalysts for Low-temperature Water-Gas Shift, Catalysis Letters, vol. 77, No. 1-3, 2001, pp. 87-95, Plenum Publishing Corporation.
Yue Li et al., Low-Temperature Water-Gas Shift Reaction over Cu-and Ni-loaded Cerium Oxide Catalysts, Applied Catalysis B: Environmental 27 (2000), pp. 179-191, Elsevier Sci. B.V., Oxford, United Kingdom.
A.F. Diwell et al., The Role of Ceria in Three-Way Catlysts, Catalysis & Automotive Pollution Control II, 1991, pp. 139-152, Elsevier Sci. Publishers B.B., Amsterdam.
Bjorn Skarman et al., Carbon Monoxide Oxidation on Nanostructured CuOx/CeO2 Composite Particles Characterized by HREM, XPS, XAS, and High-Energy Diffraction, Journal of Catalysis, 2002, vol. 211, pp. 119-131, Elsevier Sciences, USA.
Kundakovic et al., Cu- and Ag-Modified Cerium Oxide Catalysts for Methane Oxidation, Journal of Catalysis, 1998, pp. 203-221, vol. 179, Academic Press, USA.
Tschope et al., Processing and Structural Evolution of Nanocrystalline Cu-CeO2−xCatalysts, Material Science and Engineering, 1995, pp. 267-271, vol. A204, Elsevier Science S.A.
Yue Li et al., Low-Temperature Water-Gas Shift Reaction over Cu- and Ni-loaded Cerium Oxide Catalysts, Applied Catalysis B. Environmental, 2000, pp. 179-191, vol. 27, Elsevier Science B.V., United Kingdom.
Wei Liu et al., Total Oxidation of Carbon Monoxide & Methane Over Transition Metal-Fluorite Oxide Composite Catalysts, Journal of Catalysts, 1995, pp. 304-316, vol. 53, Academic Press, USA.
Wei Liu et al., Transition Metal-promoted Oxidation Catalysis By Fluorite Oxides: A Study of CO Oxidation over Cu-CeO2The Chemical Engineering Journal, 1996, pp. 283-294, vol. 64, Elsevier Science S.A.
Notification of Transmittal of the International Search Report or the Declaration for PCT/US03/27470 dated Aug. 17, 2004.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Nanocomposite copper-ceria catalysts for low temperature or... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Nanocomposite copper-ceria catalysts for low temperature or..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Nanocomposite copper-ceria catalysts for low temperature or... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3508878

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.