Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Including organic component
Reexamination Certificate
2011-01-04
2011-01-04
Mayes, Melvin C (Department: 1793)
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
Including organic component
C502S102000, C502S103000, C502S152000, C502S155000, C502S158000, C526S113000, C526S116000, C526S118000, C526S125800, C526S156000
Reexamination Certificate
active
07863210
ABSTRACT:
The present invention provides polymerization catalyst compositions employing novel dinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
REFERENCES:
patent: 3242099 (1966-03-01), Manyik
patent: 3248179 (1966-04-01), Norwood
patent: 4060480 (1977-11-01), Reed
patent: 4452910 (1984-06-01), Hopkins
patent: 4501885 (1985-02-01), Sherk
patent: 4588790 (1986-05-01), Jenkins
patent: 4794096 (1988-12-01), Ewen
patent: 4808561 (1989-02-01), Welborn
patent: 5153776 (1992-10-01), Nozawa
patent: 5352749 (1994-10-01), DeChellis
patent: 5369194 (1994-11-01), Cribbs et al.
patent: 5376611 (1994-12-01), Shveima
patent: 5436304 (1995-07-01), Griffin
patent: 5455314 (1995-10-01), Burns
patent: 5470927 (1995-11-01), Turner et al.
patent: 5473020 (1995-12-01), Peifer et al.
patent: 5492973 (1996-02-01), Peifer et al.
patent: 5492974 (1996-02-01), Peifer et al.
patent: 5492975 (1996-02-01), Peifer et al.
patent: 5565175 (1996-10-01), Hottovy
patent: 5575979 (1996-11-01), Hanson
patent: 5576259 (1996-11-01), Hasegawa
patent: 5807938 (1998-09-01), Kaneko
patent: 5869586 (1999-02-01), Riedel et al.
patent: 5919983 (1999-07-01), Rosen
patent: 6010974 (2000-01-01), Kim et al.
patent: 6107230 (2000-08-01), McDaniel
patent: 6153776 (2000-11-01), Patton et al.
patent: 6165929 (2000-12-01), McDaniel
patent: 6228790 (2001-05-01), Ting et al.
patent: 6235917 (2001-05-01), Graf et al.
patent: 6239235 (2001-05-01), Hottovy
patent: 6262191 (2001-07-01), Hottovy
patent: 6274752 (2001-08-01), Marks et al.
patent: 6291695 (2001-09-01), Marks et al.
patent: 6294494 (2001-09-01), McDaniel
patent: 6300271 (2001-10-01), McDaniel
patent: 6316553 (2001-11-01), McDaniel
patent: 6355594 (2002-03-01), McDaniel
patent: 6376415 (2002-04-01), McDaniel
patent: 6388017 (2002-05-01), McDaniel
patent: 6391816 (2002-05-01), McDaniel
patent: 6395666 (2002-05-01), McDaniel
patent: 6403732 (2002-06-01), Marks et al.
patent: 6403733 (2002-06-01), Marks et al.
patent: 6524987 (2003-02-01), Collins
patent: 6544922 (2003-04-01), Marks et al.
patent: 6548441 (2003-04-01), McDaniel
patent: 6548442 (2003-04-01), McDaniel
patent: 6576583 (2003-06-01), McDaniel
patent: 6613712 (2003-09-01), McDaniel
patent: 6632894 (2003-10-01), McDaniel
patent: 6667274 (2003-12-01), Hawley
patent: 6670299 (2003-12-01), Marks et al.
patent: 6747112 (2004-06-01), Marks et al.
patent: 6750302 (2004-06-01), McDaniel
patent: 6833415 (2004-12-01), Kendrick
patent: 7064225 (2006-06-01), Thorn et al.
patent: 7119153 (2006-10-01), Jensen et al.
patent: 7119158 (2006-10-01), Marks et al.
patent: 7160965 (2007-01-01), Marks et al.
patent: 7226886 (2007-06-01), Jayaratne
patent: 7312283 (2007-12-01), Martin et al.
patent: 7435701 (2008-10-01), Shen et al.
patent: 7495036 (2009-02-01), Farrar et al.
patent: 7517939 (2009-04-01), Yang
patent: 7619047 (2009-11-01), Yang et al.
patent: 2003/0069373 (2003-04-01), Holtcamp
patent: 2003/0134995 (2003-07-01), Marks et al.
patent: 2004/0072677 (2004-04-01), Lee
patent: 2004/0106514 (2004-06-01), Nagy et al.
patent: 2005/0043541 (2005-02-01), Walter et al.
patent: 2005/0285284 (2005-12-01), Thorn et al.
patent: 2005/0288461 (2005-12-01), Jensen et al.
patent: 2006/0183631 (2006-08-01), Lee et al.
patent: 2007/0203018 (2007-08-01), Kwon et al.
patent: 2009/0170691 (2009-07-01), Murray
patent: 2009/0171041 (2009-07-01), Murray
patent: 2009/0240010 (2009-09-01), Mcdaniel et al.
patent: 0985677 (2000-03-01), None
patent: 01743899 (2007-01-01), None
patent: 03027131 (2003-03-01), None
patent: WO 2009/085124 (2009-07-01), None
patent: WO 2009/085126 (2009-07-01), None
patent: WO 2009/085129 (2009-07-01), None
“Metathesis Route to Bridged Metallocenes”. Masamichi Ogasawara, Takashi Nagano and Tamio Hayashi. Department of Chemistry, Graduate Schoof of Science. Kyoto University.
Zr/Zr and Zr/Fe Dinuclear Complexes with flexible Bridging Ligands. Preparation by Olefin Metathesis Reaction of the monocuclear precursors and properties as Polymerization catalysts. Junpei Kuwabara et al. Organometallics 2005, 24, 2705-2712.
Formation of Dinuclear titanium and Zirconium Complexes by Olefin Metathesis-Catalytic Preparation of Organometallic catalyst system. by Jesus Cano Sierra et a. Chem. Eur.J. 2004, 9 3618-3622.
Sierra, Jesus C., et al., “Formation of Dinuclear Titanium and Zirconium Complexes by Olefin Metathesis-Catalytic Preparation of Organometallic Catalyst Systems,” Chem. Eur. J. 2003, 9, 3618-3622.
Ogasawara, Masamichi, et al., “Metathesis Route to Bridged Metallocenes,” J. Am. Chem. Soc. 2002, 124, 9068-9069.
Hüerländer, Doris, et al., “Synthesis, Structural and Chemical Characterization of Unsaturated C4-and C10-Bridged Group-4ansa-Metallocenes Obtained Through a Ring-Closing Olefin Metathesis Reaction,” Eur. J. Inorg. Chem. 2002, 2633-2642.
Hongbo, Li, et al., “Coordination Copolymerization of Severly Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts,” J. Am. Chem. Soc. 2005, 127, 14756-14768.
Murray et al., pending U.S. Appl. No. 11/965,982, filed Dec. 28, 2007 (IFW accessible).
Murray et al., pending U.S. Appl. No. 11/966,081, filed Dec. 28, 2007 (IFW accessible).
International Patent Application No. PCT/US2008/013641 Search Report (WO/2009/085124) (14 pages).
Guo, et al., Bimetallic Catalysis for Styrene Homopolymerization and Ethylene—Styrene Copolymerization. Exceptional Comonomer Selectivity and Insertion Regiochemistry. J. Am. Chem. Soc., 2004, 126(21), 6542-6543.
Kuwabara, J. et al.,Zr/ZrandZr/FeDinuclear Complexes with Flexible Bridging Ligands, Preparation by Olefin Metathesis Reaction of the Mononuclear Precursors and Properties as Polymerization Catalysts, Organometallics, 2005, 25:2705-2712.
Li, et al., Catalyst/Cocatalyst Nuclearity Effects in Single-Site Polymerization Enhanced Polyethylene Branching and α-Olefin Comonomer Enchainment in Polymerizations Mediated by Binuclear Catalysts and Cocatalysts via a New Enchainment Pathway, J.Am. Chem. Soc., 2002, 124(43), 12725-12741.
Wang, et al., Covalently Linked Heterobimetallic Catalysts for Olefin Polymerization, Organometallics, 2004, 23(22), 5112-5114.
Murray et al., pending U.S. Appl. No. 12/489,630, filed Jun. 23, 2009.
International Search Report in PCT Application No. PCT/US2010/001795, mailed Aug. 9, 2010, 7 pages.
Jayaratne Kumudini C.
Martin Joel L.
Murray Rex E.
Yang Qing
Chevron Phillips Chemical Company LP
Mayes Melvin C
Merchant & Gould P.C.
Nguyen Colette
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