N-phenylhydroxylamine polymers, and associated methods of prepar

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528 12, 528 23, 528207, 528208, 528210, 528220, 528222, 528223, 528273, 528391, 528422, 526310, 526311, 526312, 526313, D02G 300

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054984777

ABSTRACT:
Electroactive polymers are provided which contain alternating phenyl rings and nitrogen atoms, and which contain both quinoid mer units and benzenoid mer units. The polymers are formed by poly(condensation) of N-phenylhydroxylamine or derivatives thereof under anhydrous conditions in the presence of a Lewis acid catalyst. Methods for producing films, fibers and shaped articles of the polymers are provided as well.

REFERENCES:
M. Angelopoulous et al., Polyaniline: Solutions, films and oxidation state, Mol Cryst. Liq. Cryst. 160:151 (1988).
Y. Cao et al., Influence of chemical polymerization conditions on the properties of polyaniline, Polymer 30:2305 (1989).
A. G. MacDiarmid et al., Polyaniline: Protonic acid doping to the metallic regime, Mol. Cryst. Liq. Cryst. 125:309-318 (1985).
D. Vachon et al., Polyaniline is poly-para-phenyleneamineimine: proof of structure by synthesis, Synthetic Metals 18:297 (1987).

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