N-methylol 4-amino-1,2,4-triazine-5-ones

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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C07D25306

Patent

active

046147993

ABSTRACT:
N-methylol derivatives of herbicidal 4-amino-1,2,4-triazine-5-ones can be prepared by reacting formaldehyde with a 4-amino-1,2,4-triazine-5-one slurried in water under basic conditions. The N-methylol derivatives can be surface-modified by slurrying particles of the derivatives in water and treating with a strong acid or strong base, producing a product that releases the original herbicidal 4-amino-1,2,4-triazine-5-one in a controlled manner.

REFERENCES:
patent: 3920645 (1975-11-01), Schibler et al.
patent: 4067724 (1978-01-01), Draber et al.
Bann et al., Chemical Reviews, vol. 58, pp. 146-148, (1958).

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