((N-heterocyclyl)carbonyl)phosphoramidothioate ester insecticide

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...

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514 80, 514 82, 514 91, 546 22, 546 23, 548413, 548414, C07F 958, C07F 960, C07F 9572, C07F 9576, A01N 5716

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051531844

ABSTRACT:
O,S-Dailkyl ((nitrogen heterocyclyl)carbonyl)phosphoramidothioates are prepared by the reaction of O,S-dialkyl phosphoroisocyanatidothioates with selected five and six membered nitrogen heterocycles and found to be effective plant systemic and contact insecticides. Ethyl 1-(((methoxy(methylthio)phosphinyl)amino)carbonyl)-4-piperidinecarboxylate , for example, is prepared from O,S-dimethyl phosphoroisocyanatidothioate and ethyl 4-piperidinecarboxylate and found to control aster leafhopper when applied to rice plants.

REFERENCES:
Derkach et al., Zh. Obshch. Khim., 33, 1587-1591 (1963) (Chemical Abstracts, 59, 12669e (1963)).
Samarai et al., Zh. Obshch. Khim., 39, 1511-1513 (1969) (Chemical Abstracts, 71, 112323e (1969)).
Derkach et al., Zh. Obshch. Khim., 34, 3060-3063 (1964) (Chemical Abstracts, 62, 2692e (1965)).
Mel'nikov et al., Zh. Obshch. Khim., 47, 1711-1715 (1977) (Chemical Abstracts, 87, 183905n (1977)).
Alimov et al., Isv. Akad. Nauk SSSR, Ser. Khim., 1964, 187-189 (Chemical Abstracts, 60, 9144h (1964)).

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