((N-heterocyclyl)carbonyl)phosphoramidothioate ester insecticide

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...

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514 90, 514 92, 544 54, 544 57, 548112, 548113, C07D27916, C07D27912, A61K 3154, A61K 31425

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050752936

ABSTRACT:
O,S-Dialkyl ((nitrogen heterocyclyl)carbonyl)-phosphoramidothioates are prepared by the reaction of O,S-dialkyl phosphoroisocyanatidothioates with selected 5 and 6 membered nitrogen heterocycles, such as thiomorpholine and tetrahydroquinoline, and found to be effective plant systemic and contact insecticides. O,S-dimethyl ((4-thiomorpholinyl)carbonyl)phosphoramidothioate, for example, is prepared from O,S-dimethyl phosphoroisocyanatidothioate and thiomorpholine and found to control aster leafhopper when applied to rice plants.

REFERENCES:
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Derkach et al., Zh. Obshch. Khim., 33, 1587-1591 (1963).
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Derkach et al., Zh. Obshch. Khim., 34, 3060-3063 (1964).
Mel'nikov et al., (Chemical Abstracts, 87, 183905n (1977)).
Odd et al., Chemical Abstracts, vol. 89, entry 89: 129559b (1978).
Odd et al., Chemical Abstracts, vol. 88, entry 88: 70501e (1978).

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