N-fluorosulfonimides and their application as fluorinating agent

Details N-fluorosulfonimides and their application as fluorinating agent N-fluorosulfonimides and their application as fluorinating agent

1992-02-28

1993-10-19

Robinson, Allen J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

558413, 560103, 560111, 562837, 564 84, 564 85, 564 89, 564 92, 564217, 564 84, 564 85, 564 89, 564 92, 564217, 568316, 568656, 579141, 579144, 579147, C07C31115, C07C 1712, C07C 1714

Patent

active

052547329

ABSTRACT:
The invention describes N-fluorosulfonimides which are useful as fluorinating agents. The N-fluorosulfonimides are stable, easily synthesized, and allow the introduction of fluorine into organic compounds under mild conditions.

REFERENCES:
patent: 4479901 (1984-10-01), Barnette
patent: 4479901 (1984-10-01), Barnette
patent: 4828764 (1989-05-01), DesMarteau
patent: 4900887 (1980-02-01), Wilkes et al.
patent: 5003074 (1991-03-01), Allmendinger et al.
patent: 5003074 (1991-03-01), Allmendinger et al.
Differding et al. I "Electrophilic Fluorination with N-Fluorobenzene Sulfonimide, etc." Synlett395-6 (1991).
Differding et al. II, "Nucleophilic Substitution Versus Electron Transfer," etc. Tetrahedron Letters vol. 32, No. 31. pp. 3815-3818 (1991).
Differding et al III, "N-Fluorobenzene-sulfonimide, etc." Synlett, (1991) pp. 187-189.
D. Barton et al., J. Chem Soc. Perkin 1, 732 (1974).
M. Seguin et al., J. of Fluorine Chem. 15, 201 (1980).
C. Schack et al., J. of Fluorine Chem. 18, 363 (1981).
W. Barnette, J. Am. Chem. Soc. 106, 452 (1984).
J. Foropoulous, Jr. et al., Inorg. Chem. 23, 3720 (1984).
S. Lee et al., J. Am. Chem. Soc. 108, 2445 (1986).
T. Umemoto et al., Tetrahedron Letters 27(28), 3271 (1986).
S. Singh et al., J. Am. Chem. Soc. 109, 7194 (1987).
E. Differding et al., Tetrahedron Letters 29(47), 6087 (1988).
R. Banks et al., J. of Fluorine Chem. 46, 297 (1990).
T. Umemoto et al., J. Am. Chem. Soc. 112, 8563 (1990).
G. Resnati et al., J. Org. Chem. 56, 4925 (1991).
D. Desmarteau et al., J. of Fluorine Chem. 52, 7 (1991).
F. Davis et al., Tetrahedron Letters 32(13), 1631 (1991).
E. Differding et al., Synlett 3, 187 (1991).
E. Differding et al., Synlett, 395 (1991).
E. Differding et al., Tetrahedron Letters 32(31), 3815 (1991).

Affiliated with

Also associated with

Rating

N-fluorosulfonimides and their application as fluorinating agent does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with N-fluorosulfonimides and their application as fluorinating agent, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and N-fluorosulfonimides and their application as fluorinating agent will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1353142