N-cyanomethyl-2-pyridinone insecticides

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

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546287, 546291, 546292, 546296, 546297, 546298, 546300, 514345, 514346, 514348, 514349, 514350, 514351, A01N 4340, C07D21178, C07D21172, C07D21184

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active

049314521

ABSTRACT:
Substituted N-cyanomethyl-2-pyridinones were prepared by the reaction of alkali metal substituted-2-pyridinates with monohaloacetonitriles and found to possess insecticidal properties. The alkali metal substituted-2-pyridinates can be preformed or prepared from the corresponding 2-halopyridines or 2-pyridinols in the reaction medium. N-cyanomethyl-3-fluoro-5-(trifluoromethyl)-2-pyridinone, for example, was prepared from 2,3-difluoro-5-(trifluoromethyl)pyridine and found to control aster leafhoppers both on contact and systemically.

REFERENCES:
patent: 3682936 (1972-08-01), Tarba
Abramovitch, Pyridine and its Derivatives, Supplement Part 3 (1974), pp. 745-752.

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