N-Chlorosulfinylcarbamate esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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26034622, 260464, 260465D, 2604654, 2603409R, 560 10, 560 16, 560115, 560134, 560135, 560136, 560137, 560148, C07D31744, C07C14943, C07C12504, C07D30777

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042618975

ABSTRACT:
N-chlorosulfinylcarbamate esters are produced by the reaction of thionyl chloride with carbamate esters having one unsubstituted hydrogen on the carbamate nitrogen atom, preferably in the presence of a hydrogen chloride acceptor. The resulting N-chlorosulfinylcarbamate esters are useful intermediates in the preparation of pesticides having relatively low mammalian toxicity.

REFERENCES:
patent: 3663594 (1972-05-01), Brown et al.
patent: 3843688 (1974-10-01), Cleveland
patent: 3843689 (1974-10-01), Brown et al.
patent: 3914259 (1975-10-01), Brown et al.
patent: 3950374 (1976-04-01), Ueda et al.
patent: 3969407 (1976-07-01), Phillips et al.
patent: 4138423 (1979-02-01), D'Silva

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