Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...
Patent
1995-08-23
1997-03-04
Bond, Robert T.
Organic compounds -- part of the class 532-570 series
Organic compounds
Unsubstituted hydrocarbyl chain between the ring and the -c-...
540454, 540485, 540488, 544 97, 546243, 548229, 548547, 560250, 528323, C07C23331, C07D22310
Patent
active
056080573
ABSTRACT:
Proposed are an N-(.alpha.-acyloxyethyl) compound, e.g., (N-(.alpha.-acetoxyethyl)-2-pyrrolidone, which is a novel compound and can be converted into an industrially very important N-vinyl compound, e.g., N-vinyl-2-pyrrolidone, by a thermal decomposition reaction under relatively mild conditions as well as a method for the preparation of such an N-(.alpha.-acyloxyethyl) compound. The N-(.alpha.-acyloxyethyl) compound can be synthesized in a high yield by the addition reaction of an NH group-containing compound, e.g., 2-pyrrolidone, with a vinyl carboxylate, e.g., vinyl acetate, in the presence of an alkaline compound such as alkali metal hydroxides.
REFERENCES:
Chemical Abstracts, 77(8), 22, abstract No. 49091j (Aug. 1972) (abstract of JP-A-07 208 302).
Chemical Astracts, 77(8), 22, abstract no. 49092k (Aug. 1972) (abstract of JP-A-07 208 303).
Honma Yoshihiro
Kawamoto Fumiaki
Oshima Mitsuyoshi
Tanaka Shozo
Tanioka Soji
Bond Robert T.
Shin-Etsu Vinyl Acetate Co., Ltd.
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