N-alkoxymethyl benzamide derivative and manufacturing method the

Details N-alkoxymethyl benzamide derivative and manufacturing method the N-alkoxymethyl benzamide derivative and manufacturing method the

1993-10-20

1994-10-11

Kumer, Shailendra

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

548237, 548239, C09C23305, C09C23365

Patent

active

053549058

ABSTRACT:
An N-alkoxymethyl benzamide derivative represented by Formula (I); ##STR1## (In the formula, reference X indicates a halogen atom, references Y.sub.1 and Y.sub.2 indicate hydrogen atoms or halogen atoms, and may be identical or different, and reference R indicates a lower alkyl group.) and a manufacturing method for this N-alkoxymethyl benzamide derivative in which a substituted benzamide and an .alpha.-haloacetal are reacted. Furthermore, a manufacturing method for benzamide derivatives in which the N-alkoxymethyl benzamide derivative represented by Formula (I) above and benzene or a derivative thereof are reacted, and a benzamide derivative is produced. The N-alkoxymethyl benzamide derivative of the present invention is a novel compound, and possesses utility as an intermediate in the manufacturing of oxazoline derivatives which possess insecticidal and anti-mite activity, and as a starting material for the synthesis of various organic compounds and the like.

REFERENCES:
Patent Abstracts of Japan, vol. 14, No. 280 (C-729) Jun. 18, 1990, Abstract JP-A-02 085 268 (Yashima Chem. Ind. Co. Ltd.) Mar. 26, 1990.
J. P. Lokensgard et al. "Synthesis of N-(a-Methoxyalkyl) Amides from Imidates", J. Org. Chem.; 85; vol. 50 (26), pp. 5609-5611, 1985.
Drach et al. Zh. Org. Khimii, vol. 14(3), 508-513, 1978.
Hoffmann et al., Chem. Ber. 109, 1759-1768, 1976.
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Bohme et al., Arch. Pharm. 310(77), 242-248, 1977.
Balon et al., Zh. Org. Khimii, vol. 26, No. 9, 1892-1895, 1990.

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