Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-01-07
1977-07-26
Daus, Donald G.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260691, C07D26304
Patent
active
040382842
ABSTRACT:
N-substituted oxazolidines having the formula ##STR1## in which R is C.sub.1 -C.sub.10 haloalkyl, C.sub.1 -C.sub.10 alkyl or lower alkylthio; and R.sub.1 and R.sub.2 are independently hydrogen, C.sub.1 -C.sub.12 alkyl, lower alkoxyalkyl or lower alkylol; and R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen, lower alkyl, lower alkoxyalkyl or lower alkylol are prepared by reacting an oxazolidine with an acid chloride or analogous compound in the presence of a hydrogen chloride acceptor and water. The process is characterized by minimization of by-product formation.
In a preferred embodiment, the oxazolidine is prepared by reaction of an alkanolamine with an aldehyde or ketone and the water of reaction is retained in the system.
REFERENCES:
patent: 3707541 (1972-12-01), Lajiness
Sheehan et al., J. Amer. Chem. Soc. 71 1856 (1949).
Warnhoff et al., Chem. Benchte 100, 2122 (1967).
Kent et al., Organic Syn. Collective vol. III, p. 490 (1955).
Carter et al., Organic Syn. Collective vol. III, p. 167 (1955).
Bergman, Chemical Reviews 53, 310-317, 321-324.
Ackerman Joel G.
Berch Mark L.
Daus Donald G.
Stauffer Chemical Company
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