N-(5,7-dibromo-1,3-benzoxathiol-2-ylidene)-N-methylmethanaminium

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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Details

260608, 260609D, 424276, C07D32704, A61K 3140

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active

040874451

ABSTRACT:
N-(5,7-Dibromo-1,3-benzoxathiol-2-ylidene)-N-methylmethanaminium bromide and the analogous diodo iodide, new compounds, are prepared by the thermal rearrangement of O-(2,4,6-tribromophenyl)-N,N-dimethylthiocarbamate and O-(2,4,6-triiodophenyl)-N,N-dimethylthiocarbamate. The first-named compound has antimicrobial utility. Both compounds are useful as starting materials for the preparation of bis-(3,5-dibromo-2-hydroxyphenyl)disulfide and 2,4-diiodo-6-mercaptophenol, respectively, by hydrolysis of the two first-named compounds with methanolic sodium hydroxide. Both the disulfide and the mercaptophenol compounds have antimicrobial utility.

REFERENCES:
patent: 3433803 (1969-03-01), Ottmann et al.
patent: 3461168 (1969-08-01), Laufer et al.
patent: 3476791 (1969-11-01), Newman et al.
patent: 3884931 (1975-05-01), Buttner et al.

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