N-(2-mercapto-ethyl)alkanamides from H.sub.2 S and 2-H-2-oxazoli

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260307G, 260307F, 260558S, 260559T, 260562S, 260583EE, 2605705S, C07C10200, C07C 8500

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active

040862747

ABSTRACT:
N-(2-mercaptoethyl)alkanamides are produced by reacting hydrogen sulfide with 2-H-2-oxazolines or 2-alkyl-2-oxazolines. For example, N-(2-mercaptoethyl)acetamide was prepared in excellent yields by incrementally adding 2-methyl-2-oxazoline to a stirred solution of hydrogen sulfide in methanol under autogeneous pressure at about 100.degree. C.

REFERENCES:
patent: 3414620 (1968-12-01), Bresson et al.
Frump Chemical Reviews, 71, (1971), pp. 496-499.
Goldberg, J. Chem. Soc., 1948, pp. 1919-1926.
Fry, J. Org. Chem., 15, (1950), pp. 438-447.

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