Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-11-22
1978-04-25
Demers, Arthur P.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260307G, 260307F, 260558S, 260559T, 260562S, 260583EE, 2605705S, C07C10200, C07C 8500
Patent
active
040862747
ABSTRACT:
N-(2-mercaptoethyl)alkanamides are produced by reacting hydrogen sulfide with 2-H-2-oxazolines or 2-alkyl-2-oxazolines. For example, N-(2-mercaptoethyl)acetamide was prepared in excellent yields by incrementally adding 2-methyl-2-oxazoline to a stirred solution of hydrogen sulfide in methanol under autogeneous pressure at about 100.degree. C.
REFERENCES:
patent: 3414620 (1968-12-01), Bresson et al.
Frump Chemical Reviews, 71, (1971), pp. 496-499.
Goldberg, J. Chem. Soc., 1948, pp. 1919-1926.
Fry, J. Org. Chem., 15, (1950), pp. 438-447.
Kaiser Mark E.
Owen Peter W.
Demers Arthur P.
The Dow Chemical Company
White L. Wayne
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