Mutants of pyrroloquinoline quinone dependent soluble...

Chemistry: molecular biology and microbiology – Enzyme – proenzyme; compositions thereof; process for... – Oxidoreductase

Reexamination Certificate

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C435S440000, C435S004000, C435S006120, C435S069100, C435S071100, C435S026000, C435S252300, C435S320100, C536S023200

Reexamination Certificate

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07732179

ABSTRACT:
A mutant of PQQ-dependent soluble glucose dehydrogenase (s-GDH; EC 1.1.5.2) is provided with improved specificity for glucose as compared to maltose, having a substitution of threonine at position 348 by either glycine, alamine or serine, wherein said mutant additionally comprises, at least one mutation for improving the stability of the mutant and one or more mutation(s) for improving the affinity of the mutant to glucose, and/or one or more mutation(s) for further improving the specificity of the mutant for glucose as compared to maltose, and wherein position 348 correspond to the amino acid positions known from theA. calcoaceticuss-GDH wild-type sequence. Also disclosed are genes encoding such mutant s-GDH, and different applications of these s-GDH mutants, particularly for determining the concentration of glucose in a sample.

REFERENCES:
patent: 02/34919 (2002-05-01), None
patent: 2006/008132 (2006-01-01), None
Branden et al. Introduction to Protein Structure, Garland Publishing Inc., New York, p. 247, 1991.
“Molecular Engineering of PQQGDH and its Applications,” S. Igarashi et al., Archives of Biochemistry and Biophysics, vol. 428, No. 1, Aug. 1, 2004, pp. 52-63.

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