Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...
Patent
1989-01-13
1990-04-17
Zimmerman, John J.
Stock material or miscellaneous articles
All metal or with adjacent metals
Composite; i.e., plural, adjacent, spatially distinct metal...
428670, 428672, 428673, 428935, B32B 1500
Patent
active
049179675
ABSTRACT:
A multiple-layered metallic article useful for example, as costume jewelry having an intermediate "brightening layer" of bronze. A barrier layer selected from the group comprising palladium, tin, tin/zinc, rhodium, or platinum is disposed between the bronze "brightening layer" and a "top coat" layer to avoid migration of the copper component in the bronze layer to the outer surface of the article which, if left unimpeded eventually would result in a tarnishing effect to the article. As a result of the bronze intermediate layer, the article is hypo-allergenic with respect to those people having a skin sensitivity to nickel-plated or nickel-underplated metallic articles.
REFERENCES:
patent: 1001669 (1911-08-01), Monnot
patent: 2608753 (1952-09-01), Mooradian
patent: 2646616 (1953-07-01), Davignon
patent: 3162512 (1964-12-01), Robinson
patent: 3607150 (1971-09-01), McGinn
patent: 3778238 (1973-12-01), Tyler
patent: 3953246 (1976-04-01), Wilson et al.
patent: 4579761 (1986-04-01), Ruscoe et al.
Brown Jeffrey M.
Cupolo Dennis A.
Fernandez Fernando
Fonseca Geoffrey P.
Greenbaum Jean
Avon Products Inc.
Bender S. Michael
Zimmerman John J.
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