Multimetallic catalysts and their method of preparation from org

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

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502171, 502219, 502220, 502221, 208134, 208136, 208143, 208112, 208216R, B01J 2702, B01J 3112, C10G 3504, C10G 3506

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active

045130981

ABSTRACT:
Certain organometallic precursors selectively interact with surface hydroxyl groups on an inorganic oxide support such as silica, alumina or silica-alumina or to provide a uniform distribution of metal complexes on the surfaces of said support. Subsequent reduction of the support results in a high dispersion of uncomplexed metal centers to which other organometallic precursors are subsequently attached. The substantially attached organometallic precursors may be reduced and/or sulfided to yield a highly active hydrogenation catalyst having a plurality of metal species in a highly dispersed distribution.

REFERENCES:
patent: 3635761 (1972-01-01), Haag et al.
patent: 3996130 (1976-12-01), Sergeevich et al.
patent: 4059608 (1977-11-01), Calas et al.
patent: 4272406 (1981-06-01), Beach et al.
patent: 4407729 (1983-10-01), Schumacher et al.
patent: 4430443 (1984-02-01), Seiver et al.

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