Pipes and tubular conduits – Flexible – Braided – interlaced – knitted or woven
Reexamination Certificate
1999-11-10
2001-04-17
Brinson, Patrick (Department: 3752)
Pipes and tubular conduits
Flexible
Braided, interlaced, knitted or woven
C138S140000, C138S137000, C138S153000, C138S141000
Reexamination Certificate
active
06216744
ABSTRACT:
The present invention relates to a multilayer hose for transporting highly solvent chemicals and more particularly for transporting paint.
BACKGROUND OF THE INVENTION
Compared with a metal pipe, a pipe made of plastics material has the advantage of being more flexible and much lighter in weight.
However, plastics material does not have all the qualities of a metal pipe, in particular with regard to its chemical resistance to the medium that it is to convey and to its ability to withstand pressure or aggressive agents from the outside atmosphere.
Much research has led to numerous plastics material compositions for hoses being proposed for this type of application. Some of those hoses achieve excellent qualities in terms of chemical resistance or of resistance to corrosion, but they use very high quality materials and they are thus very costly. The cost of those hoses is not adapted to the price the market will bear.
OBJECTS AND SUMMARY OF THE INVENTION
The present invention proposes a hose structure which has all the strength and barrier qualities of hoses made of high quality material without having the drawback of high cost.
To this end, an object of the invention is thus to provide a multilayer hose made of plastics material for transporting highly solvent chemicals such as paint, the hose including, from the inside to the outside, a polyamide/polyolefin alloy layer, a polyurethane-based adhesive layer, a flexible plasticized layer of polyvinyl chloride, and tubular reinforcement in contact with the polyvinyl chloride.
Tests have shown that the internal layer constitutes an effective barrier against the solvents present in paint while presenting good mechanical strength in particular as a function of the temperature. However, since this material, e.g. as known on the market under the name ORGALLOY (registered trademark), is a costly material, its thickness is limited in the invention to lie in the range 0.3 mm to 1 mm. In addition, in order to obtain a hose of good mechanical quality, it is proposed that the layer outside said internal layer should be essentially a plasticized polyvinyl chloride which is low in cost and highly flexible.
To ensure that said layer of PVC bonds to the layer of polyamide/polyolefin alloy, the thinnest possible layer, i.e. a layer that is approximately 0.2 mm thick, of polyurethane and more particularly of polyurethane ester, is disposed therebetween.
Finally, in order that the hose thus constituted can mechanically withstand stresses to which it may be subjected, in particular internal pressure, it is possible to use reinforcement made of textile fibers or of metal (woven, braided, knitted . . . ), said reinforcement being disposed either at the interface between the PVC and the layer of polyurethane, or inside the layer of PVC, or outside the layer of PVC. When the reinforcement is placed inside the layer of PVC, manufacture by coextrusion requires two successive layers of PVC to be put in place, between which the reinforcement is placed. Wire reinforcement has the advantage of making the hose conductive and thus of being able to ensure the electrical continuity in a network of hoses for transporting paint, particularly in order to be able to control the flow of electric charge so as to minimize the risk of an electrical fire involving transported materials that are highly inflammable. It should also be noted that the nature of the reinforcement directly determines the breaking strength of the hose under the effect of internal pressure. By way of example, reinforcement formed by a simple wire or textile overing provides breaking strength against pressures no greater than 100 bars to 120 bars. If the covering is doubled, the strength may increase so as to withstand 250 bars. Finally, if the reinforcement is braided (simple, double . . . ), hoses can be manufactured that provide breaking strength against pressures of 600 bars to 1200 bars.
The plasticized polyvinyl chloride may optionally be cellular.
Optionally, the above-defined hose could have a final outside covering layer made from a polyurethane and designed to protect the hose from mechanical and chemical attack coming from the outside atmosphere. In an alternative method of manufacturing an electrically conductive hose, an outer covering layer made of electrically conductive polyurethane is chosen which combines, in a single layer, both the strength property of polyurethane and the property of allowing electrostatic charge to flow.
REFERENCES:
patent: 5167259 (1992-12-01), Brunnhofer
patent: 5264262 (1993-11-01), Igarashi
patent: 5348779 (1994-09-01), Igarashi
patent: 5419861 (1995-05-01), Verzaro
patent: 5622210 (1997-04-01), Crisman et al.
patent: 5706865 (1998-01-01), Douchet
patent: 5937911 (1999-08-01), Kodama et al.
Leray Fabrice
Maitay Frédéric
Peyrat Philippe
Birch & Stewart Kolasch & Birch, LLP
Brinson Patrick
Tricoflex SA
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