Electric lamp and discharge devices – With luminescent solid or liquid material – Solid-state type
Reexamination Certificate
1999-06-18
2001-07-03
Patel, Nimeshkumar D. (Department: 2879)
Electric lamp and discharge devices
With luminescent solid or liquid material
Solid-state type
C313S502000, C313S503000, C313S506000, C428S690000, C257S010000
Reexamination Certificate
active
06255774
ABSTRACT:
The field of the invention relates to organic light-emitting devices with efficient electron injecting electrodes.
Organic light-emitting devices (OLEDs) such as described in earlier U.S. Pat. No. 5,247,190 assigned to Cambridge Display Technology Limited, or in Van Slyke et al., U.S. Pat. No. 4,539,507, the contents of which are herein incorporated by reference and example, have great potential for use in various display applications. Principally, an OLED consists of an anode that injects positive charge carriers, a cathode that injects negative charge carriers and at least one organic electroluminescent layer sandwiched between the two electrodes. One of the key advantages of the OLED technology is that devices can be operated at low drive voltages, provided that suitable electro-luminescent organic layers, and electrodes with good efficiencies for the injection of positive and negative charge carriers, are used. Typically although not necessarily the anode is a thin film of, for example, indium-tin-oxide (ITO), which is a semi-transparent conductive oxide which is commercially readily available already deposited on glass or plastic substrates. The organic layer(s) is normally deposited onto the ITO-coated substrate by, for example, evaporation, or any one of spin-coating, blade-coating, dip-coating or meniscus-coating. The final step of depositing the cathode layer onto the top organic layer is normally performed by thermal evaporation or sputtering of a suitable cathode metal. Layers of Al, Ca or alloys of Mg:Ag or Mg:In or Al alloys are often used as cathode materials. In order to achieve good performance in OLEDs it is of great importance to optimise all individual layers, the anode, the cathode and the organic layer(s), as well as the interfaces between the layers.
It is very often found that the electron-injection properties of the cathode are particularly important to achieve efficient device operation. Due to the electronic structure of most organic electroluminescent materials it is very often necessary to employ cathode materials with a low work function to achieve efficient electron injection and low operating voltages. Such cathodes for OLEDs are typically alkali metals such as Li, Na, K, Rb or Cs, alkaline earth metals such as Mg, Ca, Sr or Ba or lanthanides such as Sm, Eu, Tb or Yb. These materials tend to react very readily with oxygen and moisture and particular care has to be taken on handling and/or during and after deposition onto OLEDs. Often these low work function materials are deposited as cathode layers onto OLEDs in the form of alloys whereby other alloy constituents stabilise the cathode layer; typical such alloys are for example Mg:Al, Mg:In or Mg:Ag or Al:Li. When using some of these low work function elements, for instance Ca, K, Li or Sm in pure or alloy form as OLED cathode layers these elements can diffuse into the organic layer(s) and subsequently dope the organic layer(s), cause electrical shorts or quench photo-luminescence, and therefore generally deteriorate device performance.
It is thus an object of the present invention to provide a structure, and method of fabrication for, an organic light-emitting device that incorporates low work function elements as cathodes to achieve efficient injection of negative charge carriers and low operating voltage, but minimises at least some of the problems outlined above.
According to a first aspect of the present invention there is provided an organic light-emitting device, comprising at least one layer of a light-emissive organic material arranged between an anode and a cathode for the device, wherein the cathode comprises a first layer of a conductive material which is an opaque metallic layer of high conductivity and a second layer of a conductive material having a low work function arranged between the at least one layer of organic material and the first layer of conductive material, wherein the second layer of conductive material is substantially thinner than the first layer of conductive material, having a thickness of at most 5 nm, and comprises an elemental metal, an alloy or an intermetallic compound having a work function of at most 3.7 eV.
Thus, the cathode is composed of a thin layer of an elemental metal, alloy or inter-metallic compound, with a work function of at most 3.7 eV, but preferably less than 3.2 eV. The cathode layer has a thickness of at most 5 nm, but preferably of between 0.5 and 2 nm thick. The thin, low work function cathode layer is preferably capped with another conductive layer, typically 100-500 nm thick, which provides high conductivity protection for the underlying thin, low work function layer, as well as environmental stability. Such a bi-layer electrode structure according to the first aspect of the present invention forms a cathode layer with efficient electron injection for an OLED with at least one electro-luminescent organic layer between said cathode layer and an anode layer, the anode layer for injecting positive charge carriers.
Such a structure prevents excessive doping and minimises the risk of shorting of the device structure and quenching of the electro-luminescence of the at least one layer of organic material. The first aspect of the invention also provides a method of fabricating an organic light-emitting device, comprising the steps of forming a cathode for the device over a substrate, which step comprises forming a first layer of a conductive material of high conductivity over a substrate and forming a second layer of a conductive material having a low work function over the first layer of conductive material, wherein the first layer of conductive material is an opaque metallic layer and the second layer of conductive material is substantially thinner than the first layer of conductive material having a thickness of at most 5 nm, and comprises an elemental metal, an alloy or an intermetallic compound having a work function of at most 3.7 eV, forming at least one layer of a light-emissive organic material over the cathode and forming an anode for the device over the at least one layer of organic material.
The first aspect of the invention further provides a method of fabricating an organic light-emitting device, comprising the steps of forming an anode for the device over a substrate, forming at least one layer of a light-emissive material over the anode and forming a cathode for the device over the at least one layer of organic material, which step comprises forming a second layer of a conductive material having a low work function over the at least one layer of organic material and forming a first layer of a conductive material of high conductivity over the second layer of conductive material, wherein the first layer of conductive material is an opaque metallic layer and the second layer of conductive material is substantially thinner than the first layer of conductive material having a thickness of at most 5 nm, and comprises an elemental metal, an alloy or an intermetallic compound having a work function of at most 3.7 eV.
Thus there is also provided a method of fabrication for an OLED with an efficient electron-injecting electrode in which at least one electro-luminescent organic layer, preferably either polymeric or molecular, is deposited preferably onto a supportive substrate pre-coated with an anode. The organic layer is coated in one embodiment by vacuum evaporation, with a thin layer of conductive, low work function material. This layer is at most 5 nm but preferably between 0.5 and 2 nm thick, and still more preferably about 0.5 nm. This thin layer is typically, but not essentially, an alkali metal, alkaline earth metal or a lanthanide or an alloy or inter-metallic compound incorporating one or more of said alkali metal, alkaline earth metal or lanthanide elements. The thin low work function layer is then preferably covered with a thick conductive layer of typically 100 to 500 nm thickness which provides high conductivity, protection for the underlying thin low work function layer and environmental stability, and which is preferably app
Cambridge Display Technology Ltd.
Patel Nimeshkumar D.
Williams Joseph
Wolf Greenfield & Sacks P.C.
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