Multifunctionally graded environmental barrier coatings for...

Stock material or miscellaneous articles – Composite – Of inorganic material

Reexamination Certificate

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C428S689000, C428S697000, C428S908800, C416S24100B, C416S24100B

Reexamination Certificate

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07740960

ABSTRACT:
A multilayered coating system consisting of a multicomponent zirconia-base or hafnia-base oxide top layer, an interlayer comprised of a plurality of sublayers and a bond coat layer is provided. The multilayered coating system of the present invention, with an interlayer comprised of a plurality of sublayers, provides a protective coating solution for silicon-base ceramic components exposed to very high temperatures and/or high gas flow velocity water vapor combustion environments. The plurality of sublayers affords for a multitude of interfaces that aid in phonon scattering within the coating system and thereby reduces its thermal conductivity. Furthermore, the plurality of interlayer sublayers afford a strain tolerant buffer between the top layer and substrate and thereby accommodate the thermal expansion mismatch between the oxide top layer (coefficient of thermal expansion (CTE) up to ˜8-10×10−6m/m-C) and the silicon-base ceramic substrate (CTE≈4-5×10−6m/m-C).

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