Multifunctional polymerizible alkoxy siloxane oligomers

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549215, 556458, 556460, 556467, 528 27, 528 28, 528 32, 528 33, 528 41, C07D30302, C07F 702

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active

060692596

ABSTRACT:
A composition relating to an oligomeric alkoxy siloxane substituted with polymerizible epoxy or 1-alkenyl groups, and a process for the production of that composition, are disclosed. The process entails a hydrolysis-condensation oligomerization of an epoxy- or 1-alkenyl ether-functional trialkoxy silane, catalyzed by an ion exchange resin, and separation of the resin from the resulting oligomer.

REFERENCES:
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patent: 5316695 (1994-05-01), Wilkes et al.
Crivello, J., & Mao, Z., "Synthesis of Novel Multifunctional Siloxane Oligomers using Sol-Gel Techniques and Their Photoinitiated Cationic Polymerization," Chem. Mater., vol. 9, pp. 1554-1561, 1997.
Crivello, J., & Mao, Z., "Preparation and Cationic Photopolymerization of Organic-Inorganic Hybrid Matrixes," Chem. Mater., vol. 9, pp. 1562-1569, 1997.
Crivello, J., Yang, B. & Whan-Gi, K., "Synthesis and Electron-Beam Polymerization of 1-Propenyl Ether Functional Siloxanes," Pure Appl. Chem., vol. A33(4), pp. 399-415, 1996.
Crivello, J., & Lohden, G., "Synthesis and Photopolymerization of 1-Propenyl Ether Functional Siloxanes," Chem. Mater., vol. 8, pp. 209-218, 1996.

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