Multifunctional ethynyl substituted monomers and polyarylene...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C427S385500, C526S283000, C526S285000

Reexamination Certificate

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07626059

ABSTRACT:
A compound (monomer) comprising i) one or more arylethynyl groups (A-functional groups), ii) one or more ring structures comprising two conjugated carbon-to-carbon double bonds and a leaving group L (B-functional groups), and iii) one or more ethynyl groups (C′-functional groups), characterized in that said A- and C′-functional groups are capable of reaction under cycloaddition reaction conditions with said B-functional groups to thereby form a cross-linked, polyphenylene polymer.

REFERENCES:
patent: 4400540 (1983-08-01), Reinhardt et al.
patent: 5189117 (1993-02-01), Hefner, Jr.
patent: 5270406 (1993-12-01), Earls et al.
patent: 5637669 (1997-06-01), Hefner, Jr. et al.
patent: 5965679 (1999-10-01), Godschalx et al.
patent: 6156812 (2000-12-01), Lau et al.
patent: 6172128 (2001-01-01), Lau et al.
patent: 6359091 (2002-03-01), Godschalx et al.
patent: 6653358 (2003-11-01), Bruza et al.
patent: 6887910 (2005-05-01), Bruza et al.
patent: 7381850 (2008-06-01), Godschalx et al.
patent: 2003/0027970 (2003-02-01), Haasmann et al.
patent: 2003/0083392 (2003-05-01), Bruza et al.
patent: 2003/0165625 (2003-09-01), So et al.
patent: 2004/0053033 (2004-03-01), Niu et al.
patent: 2004/0054111 (2004-03-01), Kalantar
patent: 2005/0014855 (2005-01-01), Bruza
patent: 1245586 (2002-10-01), None
patent: WO-00/31183 (2000-06-01), None
patent: WO-03/068825 (2003-08-01), None
patent: WO-03/070777 (2003-08-01), None
patent: WO 2004/089862 (2004-10-01), None
patent: WO-2004/090018 (2004-10-01), None
Baker, G. L. and J. K. Stille, “Hexaarylbenzene Units as Cross-Linking Sites for Polyquinolines”, Macromolecules, 1979, pp. 369-373, vol. 12, No. 3.
Braham, J. N., T. Hodgins, T. Katto, R. T. Kohl, and J. K. Stille, “Polyphenylenes via Bis(2-pyrones) and Diethynylbenzenes. The Effect of m- and p- Phenlene Unites in the Chain”, Macromolecules, 1978, pp. 343-346, vol. 11, No. 2.
Capek, Ignac and Jakub Chudej, “On the fine emulsion polymerization of styrene with non-ionic emulsifier,”Polymer Bulletin, vol. 1999, 43, pp. 417-424.
Donescu et al., “The Influence of Monomers upon Microemulsions with Short Chain Cosurfactant,”J. Dispersion Science and Technology, vol. 22, Nos. 2&3, pp. 231-244, 2001.
Feldman, Ken S., Robert E. Ruckle, Jr., Susan M. Ensel and Paul H. Weinreb, “Synthesis of a Chiral Binaphtyldisulfide: A Potentially Useful Reagent forCatalytic Asymmetric Syntheis”, Tetrahedron, 1992, pp. 7101-7102, vol. 33, No. 47.
Gutsche et al., “Calixarenes. 6. Synthesis of a Functionalizable Calix[4]arene in a Conformationally Rigid Cone Conformation,”J. Am. Chem. Soc., vol. 104, pp. 2652-2653 (1982).
Kraft, Amo et al., “Supramolecular liquid crystals with columnar mesophases through self-assembly of carboxylic acids around a tribasic core,”Chem. Comm, pp. 1015-1016 (2000).
Kumar, Uday and Thomas X. Neenan, “Diels-Alder Polymerization between Bis(cyclopentadienones) and Acetylenes. A Versatile Route to New Hightly Aromatic Polymers”, Macromolecules, 1995, pp. 124-130, vol. 28, No. 1.
Larpent, C. and T. F. Tadros, “Preparation of microlatex dispersions using oil-in-water microemulsions”, Colloid Polmer Science, 1991, pp. 1171-1183, vol. 269, No. 11.
Lee, Hyung-Kun et al., “Synthesis of a Nanoporous Polymer with Hexagonal Channels from Supramolecular Discotic Liquid Crystals,”Angew. Chem. Int. Ed., vol. 40, No. 14, pp. 2669-2671 (2001).
Liu, Zhi, and Jerrold Meinwald, “5-(Trimethylstannyl)-2H-pyran-2-one and 3-(Trimethylstannyl)-2H-pyran-2-one: New 2H-Pyran-2-one Synthons”, J. Org. Chem., 1996, pp. 6693-6699, vol. 61, No. 19.
McDonald et al., “Diels-Alder Reactivity of Oxygenated Dienes and Furans. Synthesis of Oxygenated Bipheynyls,”J. Chem. Soc. Perk. Trans., vol. 1, pp. 1893-1900, 1979.
Ogliaruso, Michael A. and Ernest I. Becker, “Bistetracyclones and Bishexaphenylbenzenes. II”,J. Org. Chem., 1965, pp. 3354-3360, vol. 30.
Ogliaruso, Michael A., Lewis A. Shadoff and Ernest I. Becker, “Bistetracyclones and Bishexaphenylbenzenes”,J. Org. Chem., 1963, pp. 2725-2728, vol. 28.
Puetter et al.,J. Prakt. Chem., 1951, vol. 149, pp. 183-216.
Schilling, Jr., Curtis L., Joe A. Reed, and J. K. Stille, “Diels-Alder Polymeriztions. VI. Phenylated Polyphenylenes from Bis-2-pyrones and p-Diethynylbenzene”, Macromolecules, 1969, pp. 85-88, vol. 2, No. 1.
Tong, Ling, Douglas M. Ho, Nancy J. Vogelaar, Clarence E. Schutt, and Robert A. Pascal, Jr., “The Albatrossenes: Large, Cleft-Containing, Polyphenyl Polycyclic Aromatic Hydrocarbons”, J. Am. Chem. Soc., 1997, pp. 7291-7302, vol. 119, No. 31.
Turchi , Stefania, Fodolfo Nesi, and Donatella Giomi, “Reactions of 4,5-Dicyanopyridazine with Alkynes and Enamines: a New Straghtforward Complementary Route to 4-Mono- and 4,5-Disubstituted Phthalonitriles”, Tetrahedron, 1998, pp. 1809-1816, vol. 54.
Vankerckhoven, Henk F., Yvan K. Gilliams, and J. K. Stille, “Poly(p-phenylene). The Reaction of 5,5′-p-Phenylenebis-2-pyrone with p-Diethynylbenzene”, Macromolecules, pp. 541-546, vol. 5, No. 5, 1972.
H. Warson,The Applications of Synthetic Resin Emulsions, 1972, p. 88.
Wiesler, U.-M., A. J. Berresheim, F. Morgenroth, G. Lieser, and K. Müllen, “Divergent Synthesis of Polyphenylene Dendrimers: The Role of Core and Branching Reagents upn Size and Shape”, Macromolecules, 2001, pp. 187-199, vol. 34, No. 2.
Zhong, Ben et al., “Porous ultra low-k dielectrics having ultra small pores”, Abstracts of Papers, 224thACS National Meeting, Boston, MA, Aug. 18-22, 2002, Published by the American Chemical Society.
Chemical Abstract 2001:404713.
Chemical Abstract 2003:570956.
Chemical Abstract 2002:566264.
Chemical Abstract 2000:133674.
Chemical Abstract 1999:184247.
Ciferri, Albert ed.,Liquid Crystallinity in Polymers: Principles and Fundamental Properties, Chapter 8. Liquid-Crystalline Sidechain Polymers. H. Finkelmann, pp. 315-340 (1991).

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