Multifunctional cationic photoinitiators, their preparation...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C522S053000

Reexamination Certificate

active

07598401

ABSTRACT:
Compounds of formula (I):[where: R1is a direct bond, oxygen, a group >CH2, sulphur, a group >C═O, a group —(CH2)2— or a group —N—Ra, where Rais hydrogen or alkyl; R3, R4, R5and R6are hydrogen or substituents α; R8, R9, R10and R11are hydrogen, hydroxy or alkyl; or R9and R11are joined to form a fused ring system with the benzene rings to which they are attached; R7is a direct bond, oxygen or a —CH2— group; p is 0 or 1; substituents α are: alkyl, alkoxy, alkenyl, halogen, nitrile, hydroxyl, aryl, aralkyl, aryloxy, aralkyloxy, arylalkenyl, cycloalkyl, carboxy, carboxyalkoxy, alkoxycarbonyl, aryloxycarbonyl, alkylcarbonyloxy, alkanesulphonyl, arenesulphonyl, alkanoyl or arylcarbonyl; n is 1 to 12; R12is hydrogen, methyl or ethyl; A is a group —[O(CHR13CHR14)a]y—, —[O(CH2)bCO]y—, or —[O(CH2)bCO](y−1)—[O(CHR13CHR14)a]—, where:one of R13and R14is hydrogen and the other is hydrogen, methyl or ethyl; a is 1 to 2; b is 4 to 5; Q is a residue of a polyhydroxy compound having from 2 to 6 hydroxy groups; x is a number greater than 1 but no greater than the number of available hydroxyl groups in Q; y is a number from 1 to 10; andX−is an anion]; and esters thereof are useful as cationic photoinitiators, especially for use in surface coating applications, such as printing inks and varnishes, and which are intended to be cured by polymerisation initiated by radiation.

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